X-ray structure of a Ni(II)-tri-phenoxyl radical complex

Laurent Benisvy, Galina M. Zats, Ohad Fleker, Dmitry S. Yufit, Maylis Orio, Galina Romanenko, Victor Ovcharenko

Research output: Contribution to journalArticlepeer-review

4 Scopus citations


The diimino-diphenolato neutral square-planar Ni(ii) complex, NiL2, is readily oxidised with 2 equiv. of Ag[SbF6], to produce an unprecedented octahedral Ni(ii) tris(phenoxyl) radical complex, [Ni(L)3][SbF6]2. This study reveals, for the first time, the X-ray structure of a metal-tri-phenoxyl radical complex.

Original languageEnglish
Pages (from-to)17924-17926
Number of pages3
JournalDalton Transactions
Issue number41
StatePublished - 7 Nov 2015

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