White lines in x-ray absorption

M. Brown; R. E. Peierls; E. A. Stern

doi:10.1103/PhysRevB.15.738

White lines in x-ray absorption

M. Brown
, R. E. Peierls
, E. A. Stern

Research output: Contribution to journal › Article › peer-review

320 Scopus citations

Abstract

A quantitative discussion of the white line at the L3 edge of platinum and its absence at the L2 edge in x-ray absorption is presented. The predominance of d52 character in the hole in the atomic 5d shell of Pt is shown to persist in the unoccupied portion of the d band of the metal. The total weight in the L3-edge white line is calculated and found consistent with the experimental value. A brief presentation of some experimental results is given including some suggestion of the range of validity of the sudden approximation in x-ray absorption.

Original language	English
Pages (from-to)	738-744
Number of pages	7
Journal	Physical Review B
Volume	15
Issue number	2
DOIs	https://doi.org/10.1103/PhysRevB.15.738
State	Published - 1977
Externally published	Yes

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10.1103/PhysRevB.15.738

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abstract = "A quantitative discussion of the white line at the L3 edge of platinum and its absence at the L2 edge in x-ray absorption is presented. The predominance of d52 character in the hole in the atomic 5d shell of Pt is shown to persist in the unoccupied portion of the d band of the metal. The total weight in the L3-edge white line is calculated and found consistent with the experimental value. A brief presentation of some experimental results is given including some suggestion of the range of validity of the sudden approximation in x-ray absorption.",

author = "M. Brown and Peierls, \{R. E.\} and Stern, \{E. A.\}",

year = "1977",

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AB - A quantitative discussion of the white line at the L3 edge of platinum and its absence at the L2 edge in x-ray absorption is presented. The predominance of d52 character in the hole in the atomic 5d shell of Pt is shown to persist in the unoccupied portion of the d band of the metal. The total weight in the L3-edge white line is calculated and found consistent with the experimental value. A brief presentation of some experimental results is given including some suggestion of the range of validity of the sudden approximation in x-ray absorption.

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White lines in x-ray absorption

Abstract

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