When the ligands go marching in: A step-scan Fourier transform infrared spectroscopic study of ligand attack at the transient species W(CO)5(CyH)

Richard H. Schultz; S. Krav-Ami

doi:10.1039/a807672c

When the ligands go marching in: A step-scan Fourier transform infrared spectroscopic study of ligand attack at the transient species W(CO)₅(CyH)

Richard H. Schultz, S. Krav-Ami

Department of Chemistry

Scientific Equipment Corporation

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Time-resolved step-scan Fourier transform infrared spectroscopy (S²FTIR) is used to probe the reactions of the transient species W(CO)₅(CyH), produced by photolysis of W(CO)₆ in cyclohexane solution, with a series of incoming ligands L. This study marks the first time that S²FTIR has been used to obtain mechanistic information for an irreversible chemical process.

Original language	English
Pages (from-to)	115-117
Number of pages	3
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	2
DOIs	https://doi.org/10.1039/a807672c
State	Published - 21 Jan 1999

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abstract = "Time-resolved step-scan Fourier transform infrared spectroscopy (S2FTIR) is used to probe the reactions of the transient species W(CO)5(CyH), produced by photolysis of W(CO)6 in cyclohexane solution, with a series of incoming ligands L. This study marks the first time that S2FTIR has been used to obtain mechanistic information for an irreversible chemical process.",

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When the ligands go marching in: A step-scan Fourier transform infrared spectroscopic study of ligand attack at the transient species W(CO)₅(CyH)

Abstract

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