TY - JOUR
T1 - Vilsmeier-Haack Reagents. Novel Electrophiles for the One-Step Formylation of O-Silylated Ethers to O-Formates
AU - Lellouche, Jean Paul
AU - Kotlyar, Vadim
PY - 2004/2/18
Y1 - 2004/2/18
N2 - Various O-silylated substrates were effectively converted in one-step to their corresponding O-formates using electrophilic racemic and homochiral Vilsmeier-Haack reagents. Reactivity trends of these transformations were examined that, specifically, emphasized their synthetic potential.
AB - Various O-silylated substrates were effectively converted in one-step to their corresponding O-formates using electrophilic racemic and homochiral Vilsmeier-Haack reagents. Reactivity trends of these transformations were examined that, specifically, emphasized their synthetic potential.
KW - Deprotection of O-silyl ethers
KW - Formyl glycosides
KW - One-step deprotection
KW - Preparation of O-formates
KW - Vilsmeier-Haack complexes
UR - http://www.scopus.com/inward/record.url?scp=1442286541&partnerID=8YFLogxK
U2 - 10.1055/s-2004-815435
DO - 10.1055/s-2004-815435
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AN - SCOPUS:1442286541
SN - 0936-5214
SP - 564
EP - 571
JO - Synlett
JF - Synlett
IS - 3
ER -