Treatment of deviation from symmetry using generalized perturbation theory

H. Friedmann, U. Landman

Research output: Contribution to journalArticlepeer-review

Abstract

A partitioning technique is developed according to which the Hamiltonian is split into an unperturbed part, which is totally symmetrical with respect to a chosen group of symmetry operations and a symmetry-breaking perturbation coupling the states of different symmetries. Various consequences, applications, and extensions of this method are discussed.

Original languageEnglish
Pages (from-to)477-479
Number of pages3
JournalChemical Physics Letters
Volume1
Issue number10
DOIs
StatePublished - Dec 1967
Externally publishedYes

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