Total synthesis of (11R, 12S)-diHETE

Agnès Gigou; Jean Pierre Beaucourt; Jean Paul Lellouche; René Gree

doi:10.1016/s0040-4039(00)74847-7

Total synthesis of (11R, 12S)-diHETE

Agnès Gigou
, Jean Pierre Beaucourt
, Jean Paul Lellouche
, René Gree

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

The first total synthesis of (11R, 12S) diHETE is reported. The key step is the highly chemio- and stereoselective osmylation of a double bond in a trienyne system selectively complexed by an Fe(CO)₃ group.

Original language	English
Pages (from-to)	635-638
Number of pages	4
Journal	Tetrahedron Letters
Volume	32
Issue number	5
DOIs	https://doi.org/10.1016/s0040-4039(00)74847-7
State	Published - 28 Jan 1991
Externally published	Yes

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title = "Total synthesis of (11R, 12S)-diHETE",

abstract = "The first total synthesis of (11R, 12S) diHETE is reported. The key step is the highly chemio- and stereoselective osmylation of a double bond in a trienyne system selectively complexed by an Fe(CO)3 group.",

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AU - Gigou, Agnès

AU - Beaucourt, Jean Pierre

AU - Lellouche, Jean Paul

AU - Gree, René

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Y1 - 1991/1/28

N2 - The first total synthesis of (11R, 12S) diHETE is reported. The key step is the highly chemio- and stereoselective osmylation of a double bond in a trienyne system selectively complexed by an Fe(CO)3 group.

AB - The first total synthesis of (11R, 12S) diHETE is reported. The key step is the highly chemio- and stereoselective osmylation of a double bond in a trienyne system selectively complexed by an Fe(CO)3 group.

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JO - Tetrahedron Letters

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Total synthesis of (11R, 12S)-diHETE

Abstract

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