Topotactic elimination of water across a C-C ligand bond in a dense 3-D metal-organic framework

Hamish H.M. Yeung; Monica Kosa; John M. Griffin; Clare P. Grey; Dan T. Major; Anthony K. Cheetham

doi:10.1039/c4cc06136e

Topotactic elimination of water across a C-C ligand bond in a dense 3-D metal-organic framework

Hamish H.M. Yeung, Monica Kosa, John M. Griffin, Clare P. Grey, Dan T. Major, Anthony K. Cheetham

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Upon heating, lithium l-malate undergoes topotactic dehydration to form a phase containing the unsaturated fumarate ligand, in which the original 3-D framework remains intact. Insight into this unusual transformation has been obtained by single crystal X-ray diffraction, MAS-NMR, in situ powder X-ray diffraction and DFT calculations.

Original language	English
Pages (from-to)	13292-13295
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	87
DOIs	https://doi.org/10.1039/c4cc06136e
State	Published - 11 Nov 2014

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© the Partner Organisations 2014.

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abstract = "Upon heating, lithium l-malate undergoes topotactic dehydration to form a phase containing the unsaturated fumarate ligand, in which the original 3-D framework remains intact. Insight into this unusual transformation has been obtained by single crystal X-ray diffraction, MAS-NMR, in situ powder X-ray diffraction and DFT calculations.",

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AU - Yeung, Hamish H.M.

AU - Kosa, Monica

AU - Griffin, John M.

AU - Grey, Clare P.

AU - Major, Dan T.

AU - Cheetham, Anthony K.

PY - 2014/11/11

Y1 - 2014/11/11

N2 - Upon heating, lithium l-malate undergoes topotactic dehydration to form a phase containing the unsaturated fumarate ligand, in which the original 3-D framework remains intact. Insight into this unusual transformation has been obtained by single crystal X-ray diffraction, MAS-NMR, in situ powder X-ray diffraction and DFT calculations.

AB - Upon heating, lithium l-malate undergoes topotactic dehydration to form a phase containing the unsaturated fumarate ligand, in which the original 3-D framework remains intact. Insight into this unusual transformation has been obtained by single crystal X-ray diffraction, MAS-NMR, in situ powder X-ray diffraction and DFT calculations.

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Topotactic elimination of water across a C-C ligand bond in a dense 3-D metal-organic framework

Abstract

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