Thermal expansion of surface-frozen monolayers of semifluorinated alkanes

E. Sloutskin; H. Kraack; B. Ocko; J. Ellmann; M. Möller; P. Lo Nostro; M. Deutsch

doi:10.1021/la0156309

Thermal expansion of surface-frozen monolayers of semifluorinated alkanes

E. Sloutskin, H. Kraack, B. Ocko, J. Ellmann, M. Möller, P. Lo Nostro, M. Deutsch

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Abstract

The linear coefficient of thermal expansion of a quasi-2D surface-frozen crystalline layer is measured, using surface X-ray diffraction, for three different semifiuorinated alkane diblocks. The values obtained are in good agreement with those of surface-frozen monolayers of fully protonated alkanes. An unexpected strong dependence on the protonated block'S length is found and discussed.

Original language	English
Pages (from-to)	1963-1967
Number of pages	5
Journal	Langmuir
Volume	18
Issue number	6
DOIs	https://doi.org/10.1021/la0156309
State	Published - 19 Mar 2002

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title = "Thermal expansion of surface-frozen monolayers of semifluorinated alkanes",

abstract = "The linear coefficient of thermal expansion of a quasi-2D surface-frozen crystalline layer is measured, using surface X-ray diffraction, for three different semifiuorinated alkane diblocks. The values obtained are in good agreement with those of surface-frozen monolayers of fully protonated alkanes. An unexpected strong dependence on the protonated block'S length is found and discussed.",

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AU - Sloutskin, E.

AU - Kraack, H.

AU - Ocko, B.

AU - Ellmann, J.

AU - Möller, M.

AU - Lo Nostro, P.

AU - Deutsch, M.

PY - 2002/3/19

Y1 - 2002/3/19

N2 - The linear coefficient of thermal expansion of a quasi-2D surface-frozen crystalline layer is measured, using surface X-ray diffraction, for three different semifiuorinated alkane diblocks. The values obtained are in good agreement with those of surface-frozen monolayers of fully protonated alkanes. An unexpected strong dependence on the protonated block'S length is found and discussed.

AB - The linear coefficient of thermal expansion of a quasi-2D surface-frozen crystalline layer is measured, using surface X-ray diffraction, for three different semifiuorinated alkane diblocks. The values obtained are in good agreement with those of surface-frozen monolayers of fully protonated alkanes. An unexpected strong dependence on the protonated block'S length is found and discussed.

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EP - 1967

JO - Langmuir

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Thermal expansion of surface-frozen monolayers of semifluorinated alkanes

Abstract

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