Thermal decomposition of commercial silicone oil to produce high yield high surface area SiC nanorods

This article reports on the synthesis of high surface area (563m ²/g) β-SiC nanorods by thermal decomposition of commercial silicone oil at a relatively low reaction temperature (800 °C) in a closed Swagelok cell. High yield (75%) of SiC nanorods are obtained in this one-stage, solvent-, catalyst-, and template-free synthesis technique that runs at a relative low temperature and employs cheap single-precursor. The morphological (TEM, HR-SEM), compositional (CHNS, EDX, SAEDX]), structural (XRD, HR-TEM, and ED), thermal (TGA) characterizations and surface area analysis are carried out for the obtained SiC nanorods. The possibility of hydrogen storage in this high surface area nano-SiC rods are also tested and reported for the first time.