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Theory of simultaneous electrochemical oxidation and protonation of polyaniline: Polaronic model

  • Russian Academy of Sciences

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

A model for electrochemical doping of polyaniline taking into account the presence of protons and polarons in the polymer bulk is considered. The essential feature of this model is the account of the interactions between these species. The expressions for oxidation and protonation isotherms and the corresponding voltammograms over a wide range of electrode potential and solution pH are derived. The theoretical results seem to be in qualitative agreement with the literature experimental data.

Original languageEnglish
Pages (from-to)1023-1026
Number of pages4
JournalJournal of the Chemical Society - Faraday Transactions
Volume88
Issue number7
DOIs
StatePublished - 1992
Externally publishedYes

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