TY - JOUR
T1 - The solution structure and fluxional behaviour of cyclic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile)
AU - Howell, James A.S.
AU - Walton, Gary
AU - Tirvengadum, Marie Claire
AU - Squibb, Adrian D.
AU - Palin, Michael G.
AU - McArdle, Patrick
AU - Cunningham, Desmond
AU - Goldschmidt, Zeev
AU - Gottlieb, Hugo
AU - Strul, Gila
PY - 1991/1/8
Y1 - 1991/1/8
N2 - Variable temperature 13C and 31P NMR spectroscopy has been used to establish solution structures and conformer populations for a variety of cylic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile). The solid state structures of (2,3-dimethylbutadiene)Fe(CO)2PPh3 and (trans,trans-2,4-hexadiene)Fe(CO)2PPh3 have been determined and used as a basis for molecular modelling of steric effects in these complexes.
AB - Variable temperature 13C and 31P NMR spectroscopy has been used to establish solution structures and conformer populations for a variety of cylic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile). The solid state structures of (2,3-dimethylbutadiene)Fe(CO)2PPh3 and (trans,trans-2,4-hexadiene)Fe(CO)2PPh3 have been determined and used as a basis for molecular modelling of steric effects in these complexes.
UR - http://www.scopus.com/inward/record.url?scp=0002308220&partnerID=8YFLogxK
U2 - 10.1016/0022-328x(91)86199-z
DO - 10.1016/0022-328x(91)86199-z
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AN - SCOPUS:0002308220
SN - 0022-328X
VL - 401
SP - 91
EP - 123
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1-2
ER -