The rate constant of the F + NH3 reaction: Inverse temperature dependence

Avigdor Persky

doi:10.1016/j.cplett.2007.03.032

The rate constant of the F + NH₃ reaction: Inverse temperature dependence

Avigdor Persky

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

The rate constant of the F + NH₃ reaction has been determined in the temperature range 276-327 K, using a discharge-flow mass spectrometric technique. A relative rate method has been employed, using the F + CH₄ reaction as a reference reaction. The rate of the F + NH₃ reaction was found to increase significantly as the temperature is lowered. The present results are compared with previous published experimental and theoretical results. The inverse temperature dependence reported in this study is significantly stronger than what has been reported until now for any other reaction.

Original language	English
Pages (from-to)	3-7
Number of pages	5
Journal	Chemical Physics Letters
Volume	439
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2007.03.032
State	Published - 4 May 2007

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10.1016/j.cplett.2007.03.032

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abstract = "The rate constant of the F + NH3 reaction has been determined in the temperature range 276-327 K, using a discharge-flow mass spectrometric technique. A relative rate method has been employed, using the F + CH4 reaction as a reference reaction. The rate of the F + NH3 reaction was found to increase significantly as the temperature is lowered. The present results are compared with previous published experimental and theoretical results. The inverse temperature dependence reported in this study is significantly stronger than what has been reported until now for any other reaction.",

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AB - The rate constant of the F + NH3 reaction has been determined in the temperature range 276-327 K, using a discharge-flow mass spectrometric technique. A relative rate method has been employed, using the F + CH4 reaction as a reference reaction. The rate of the F + NH3 reaction was found to increase significantly as the temperature is lowered. The present results are compared with previous published experimental and theoretical results. The inverse temperature dependence reported in this study is significantly stronger than what has been reported until now for any other reaction.

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The rate constant of the F + NH₃ reaction: Inverse temperature dependence

Abstract

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