TY - JOUR
T1 - The rate constant of the F + NH3 reaction
T2 - Inverse temperature dependence
AU - Persky, Avigdor
PY - 2007/5/4
Y1 - 2007/5/4
N2 - The rate constant of the F + NH3 reaction has been determined in the temperature range 276-327 K, using a discharge-flow mass spectrometric technique. A relative rate method has been employed, using the F + CH4 reaction as a reference reaction. The rate of the F + NH3 reaction was found to increase significantly as the temperature is lowered. The present results are compared with previous published experimental and theoretical results. The inverse temperature dependence reported in this study is significantly stronger than what has been reported until now for any other reaction.
AB - The rate constant of the F + NH3 reaction has been determined in the temperature range 276-327 K, using a discharge-flow mass spectrometric technique. A relative rate method has been employed, using the F + CH4 reaction as a reference reaction. The rate of the F + NH3 reaction was found to increase significantly as the temperature is lowered. The present results are compared with previous published experimental and theoretical results. The inverse temperature dependence reported in this study is significantly stronger than what has been reported until now for any other reaction.
UR - https://www.scopus.com/pages/publications/34247249764
U2 - 10.1016/j.cplett.2007.03.032
DO - 10.1016/j.cplett.2007.03.032
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AN - SCOPUS:34247249764
SN - 0009-2614
VL - 439
SP - 3
EP - 7
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1-3
ER -