The one-electron reduction of a multi-centred iron(III) polyoxometallate. A pulse radiolysis study

Inna Popivker; Israel Zilbermann; Eric Maimon; Haim Cohen; Dan Meyerstein

doi:10.1016/j.inoche.2011.05.029

The one-electron reduction of a multi-centred iron(III) polyoxometallate. A pulse radiolysis study

Inna Popivker, Israel Zilbermann, Eric Maimon, Haim Cohen, Dan Meyerstein

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The single electron reduction of the complex [P₈W ₄₈O₁₈₄Fe₁₆(OH)₂₈(H ₂O)₄]^20- by the hydrated electron yields the mixed-valence complex [P₈W₄₈O₁₈₄Fe ^IIFe^III₁₅(OH)₂₈-(H ₂O)₄]^21- which has an intervalence charge transfer band in the near I.R. This result points out that there is a strong interaction between the iron centres. The formation of [P₈W ₄₈O₁₈₄Fe^IIFe^III₁₅-(OH) ₂₈(H₂O)₄]^21- is followed by the loss of the Fe^II centre and the rearrangement of the remaining Fe ₁₅^III cluster.

Original language	English
Pages (from-to)	1390-1392
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	9
DOIs	https://doi.org/10.1016/j.inoche.2011.05.029
State	Published - Sep 2011
Externally published	Yes

Bibliographical note

Funding Information:
This study was supported in part by a grant from the Budgeting and Planning Committee of The Council of Higher Education of Israel and the Israel Atomic Energy Commission .

Funding

This study was supported in part by a grant from the Budgeting and Planning Committee of The Council of Higher Education of Israel and the Israel Atomic Energy Commission .

Funders	Funder number
Planning and Budgeting Committee of the Council for Higher Education of Israel
Israel Atomic Energy Commission

Keywords

Inter-valence charge transfer
Iron oxide nanocluster
Mixed-valence
Polyoxometallates
Pulse-radiolysis
Single electron reduction

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10.1016/j.inoche.2011.05.029

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title = "The one-electron reduction of a multi-centred iron(III) polyoxometallate. A pulse radiolysis study",

abstract = "The single electron reduction of the complex [P8W 48O184Fe16(OH)28(H 2O)4]20- by the hydrated electron yields the mixed-valence complex [P8W48O184Fe IIFeIII15(OH)28-(H 2O)4]21- which has an intervalence charge transfer band in the near I.R. This result points out that there is a strong interaction between the iron centres. The formation of [P8W 48O184FeIIFeIII15-(OH) 28(H2O)4]21- is followed by the loss of the FeII centre and the rearrangement of the remaining Fe 15III cluster.",

keywords = "Inter-valence charge transfer, Iron oxide nanocluster, Mixed-valence, Polyoxometallates, Pulse-radiolysis, Single electron reduction",

author = "Inna Popivker and Israel Zilbermann and Eric Maimon and Haim Cohen and Dan Meyerstein",

note = "Funding Information: This study was supported in part by a grant from the Budgeting and Planning Committee of The Council of Higher Education of Israel and the Israel Atomic Energy Commission .",

year = "2011",

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doi = "10.1016/j.inoche.2011.05.029",

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journal = "Inorganic Chemistry Communications",

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T1 - The one-electron reduction of a multi-centred iron(III) polyoxometallate. A pulse radiolysis study

AU - Popivker, Inna

AU - Zilbermann, Israel

AU - Maimon, Eric

AU - Cohen, Haim

AU - Meyerstein, Dan

N1 - Funding Information: This study was supported in part by a grant from the Budgeting and Planning Committee of The Council of Higher Education of Israel and the Israel Atomic Energy Commission .

PY - 2011/9

Y1 - 2011/9

N2 - The single electron reduction of the complex [P8W 48O184Fe16(OH)28(H 2O)4]20- by the hydrated electron yields the mixed-valence complex [P8W48O184Fe IIFeIII15(OH)28-(H 2O)4]21- which has an intervalence charge transfer band in the near I.R. This result points out that there is a strong interaction between the iron centres. The formation of [P8W 48O184FeIIFeIII15-(OH) 28(H2O)4]21- is followed by the loss of the FeII centre and the rearrangement of the remaining Fe 15III cluster.

AB - The single electron reduction of the complex [P8W 48O184Fe16(OH)28(H 2O)4]20- by the hydrated electron yields the mixed-valence complex [P8W48O184Fe IIFeIII15(OH)28-(H 2O)4]21- which has an intervalence charge transfer band in the near I.R. This result points out that there is a strong interaction between the iron centres. The formation of [P8W 48O184FeIIFeIII15-(OH) 28(H2O)4]21- is followed by the loss of the FeII centre and the rearrangement of the remaining Fe 15III cluster.

KW - Inter-valence charge transfer

KW - Iron oxide nanocluster

KW - Mixed-valence

KW - Polyoxometallates

KW - Pulse-radiolysis

KW - Single electron reduction

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SN - 1387-7003

VL - 14

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JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

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The one-electron reduction of a multi-centred iron(III) polyoxometallate. A pulse radiolysis study

Abstract

Bibliographical note

Funding

Keywords

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