The magnetic circular dichroism of 1-azabicyclo[2,2,2]octane (ABCO) in the n0→3p region

Aharon Gedanken

doi:10.1063/1.450201

The magnetic circular dichroism of 1-azabicyclo[2,2,2]octane (ABCO) in the n₀→3p region

Aharon Gedanken

Department of Chemistry

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Abstract

An MCD and absorption spectra measured in the energy region of the second excited state of 1-azabicyclo[2,2,2] octane (ABCO) reveal large positive A terms. Simple calculations of the magnetic moment of a ¹E excited state yield also a positive sign for the A terms. A small negative B term is observed 355 cm^-1 below the origin of the ¹E state. Based on B term calculations we assign it as the ¹A₁→ ¹A₁ transition (n₀→-3p_z). The results are compared with a recent MPI study in the same energy range.

Original language	English
Pages (from-to)	3634-3637
Number of pages	4
Journal	Journal of Chemical Physics
Volume	84
Issue number	7
DOIs	https://doi.org/10.1063/1.450201
State	Published - 1985

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abstract = "An MCD and absorption spectra measured in the energy region of the second excited state of 1-azabicyclo[2,2,2] octane (ABCO) reveal large positive A terms. Simple calculations of the magnetic moment of a 1E excited state yield also a positive sign for the A terms. A small negative B term is observed 355 cm-1 below the origin of the 1E state. Based on B term calculations we assign it as the 1A1→ 1A1 transition (n0→-3pz). The results are compared with a recent MPI study in the same energy range.",

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AB - An MCD and absorption spectra measured in the energy region of the second excited state of 1-azabicyclo[2,2,2] octane (ABCO) reveal large positive A terms. Simple calculations of the magnetic moment of a 1E excited state yield also a positive sign for the A terms. A small negative B term is observed 355 cm-1 below the origin of the 1E state. Based on B term calculations we assign it as the 1A1→ 1A1 transition (n0→-3pz). The results are compared with a recent MPI study in the same energy range.

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The magnetic circular dichroism of 1-azabicyclo[2,2,2]octane (ABCO) in the n₀→3p region

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