Abstract
An MCD and absorption spectra measured in the energy region of the second excited state of 1-azabicyclo[2,2,2] octane (ABCO) reveal large positive A terms. Simple calculations of the magnetic moment of a 1E excited state yield also a positive sign for the A terms. A small negative B term is observed 355 cm-1 below the origin of the 1E state. Based on B term calculations we assign it as the 1A1→ 1A1 transition (n0→-3pz). The results are compared with a recent MPI study in the same energy range.
Original language | English |
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Pages (from-to) | 3634-3637 |
Number of pages | 4 |
Journal | Journal of Chemical Physics |
Volume | 84 |
Issue number | 7 |
DOIs | |
State | Published - 1985 |