The electrochemical behaviour of 1,3-dioxolane-LiClO4 solutions-I. Uncontaminated solutions

Doron Aurbach; Orit Youngman; Yosef Gofer; Arie Meitav

doi:10.1016/0013-4686(90)87055-7

The electrochemical behaviour of 1,3-dioxolane-LiClO₄ solutions-I. Uncontaminated solutions

Doron Aurbach
, Orit Youngman
, Yosef Gofer
, Arie Meitav

Department of Chemistry

Bar-Ilan University
Lithium Plant, Tadiran Ltd

Research output: Contribution to journal › Article › peer-review

216 Scopus citations

Abstract

The electrochemical behavior of 1,3-dioxolane (DN)-LiClO₄ solutions with lithium and noble metal (eg gold, platinum) electrodes was investigated using surface sensitive FT-ir, scanning electron microscopy (SEM), X-ray microanalysis and electrochemical techniques. It was found that the salt and the solvent react with lithium or noble metal electrodes at low potentials to form surface films which control the electrochemical behavior of these systems. Their structure and mechanism of formation, as well as correlation between surface chemistry, surface morphology, and cycling efficiency of lithium electrodes in these solutions are discussed in detail.

Original language	English
Pages (from-to)	625-638
Number of pages	14
Journal	Electrochimica Acta
Volume	35
Issue number	3
DOIs	https://doi.org/10.1016/0013-4686(90)87055-7
State	Published - Mar 1990

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10.1016/0013-4686(90)87055-7

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title = "The electrochemical behaviour of 1,3-dioxolane-LiClO4 solutions-I. Uncontaminated solutions",

abstract = "The electrochemical behavior of 1,3-dioxolane (DN)-LiClO4 solutions with lithium and noble metal (eg gold, platinum) electrodes was investigated using surface sensitive FT-ir, scanning electron microscopy (SEM), X-ray microanalysis and electrochemical techniques. It was found that the salt and the solvent react with lithium or noble metal electrodes at low potentials to form surface films which control the electrochemical behavior of these systems. Their structure and mechanism of formation, as well as correlation between surface chemistry, surface morphology, and cycling efficiency of lithium electrodes in these solutions are discussed in detail.",

author = "Doron Aurbach and Orit Youngman and Yosef Gofer and Arie Meitav",

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AU - Meitav, Arie

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AB - The electrochemical behavior of 1,3-dioxolane (DN)-LiClO4 solutions with lithium and noble metal (eg gold, platinum) electrodes was investigated using surface sensitive FT-ir, scanning electron microscopy (SEM), X-ray microanalysis and electrochemical techniques. It was found that the salt and the solvent react with lithium or noble metal electrodes at low potentials to form surface films which control the electrochemical behavior of these systems. Their structure and mechanism of formation, as well as correlation between surface chemistry, surface morphology, and cycling efficiency of lithium electrodes in these solutions are discussed in detail.

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The electrochemical behaviour of 1,3-dioxolane-LiClO₄ solutions-I. Uncontaminated solutions

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