TY - JOUR
T1 - The electrochemical behaviour of 1,3-dioxolane-LiClO4 solutions-I. Uncontaminated solutions
AU - Aurbach, Doron
AU - Youngman, Orit
AU - Gofer, Yosef
AU - Meitav, Arie
PY - 1990/3
Y1 - 1990/3
N2 - The electrochemical behavior of 1,3-dioxolane (DN)-LiClO4 solutions with lithium and noble metal (eg gold, platinum) electrodes was investigated using surface sensitive FT-ir, scanning electron microscopy (SEM), X-ray microanalysis and electrochemical techniques. It was found that the salt and the solvent react with lithium or noble metal electrodes at low potentials to form surface films which control the electrochemical behavior of these systems. Their structure and mechanism of formation, as well as correlation between surface chemistry, surface morphology, and cycling efficiency of lithium electrodes in these solutions are discussed in detail.
AB - The electrochemical behavior of 1,3-dioxolane (DN)-LiClO4 solutions with lithium and noble metal (eg gold, platinum) electrodes was investigated using surface sensitive FT-ir, scanning electron microscopy (SEM), X-ray microanalysis and electrochemical techniques. It was found that the salt and the solvent react with lithium or noble metal electrodes at low potentials to form surface films which control the electrochemical behavior of these systems. Their structure and mechanism of formation, as well as correlation between surface chemistry, surface morphology, and cycling efficiency of lithium electrodes in these solutions are discussed in detail.
UR - http://www.scopus.com/inward/record.url?scp=0025389044&partnerID=8YFLogxK
U2 - 10.1016/0013-4686(90)87055-7
DO - 10.1016/0013-4686(90)87055-7
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AN - SCOPUS:0025389044
SN - 0013-4686
VL - 35
SP - 625
EP - 638
JO - Electrochimica Acta
JF - Electrochimica Acta
IS - 3
ER -