The Degenerate Rearrangement of the Benzo[6,7]bicyclo[3.2.2]nonatrienyl Anion. Relative Stability of a Benzylic and an Allylic Anion

M. V. Moncur; John B. Grutzner; A. Eisenstadt

doi:10.1021/jo00924a042

The Degenerate Rearrangement of the Benzo[6,7]bicyclo[3.2.2]nonatrienyl Anion. Relative Stability of a Benzylic and an Allylic Anion

M. V. Moncur
, John B. Grutzner
, A. Eisenstadt

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The benzo-6,7-bicyclo[3.2.2]nonatrienyl anion undergoes a facile degenerate 7-carbon scrambling detected using ¹³C nmr techniques; the rearrangement has been used to probe relative anion stabilities.

Original language	English
Pages (from-to)	1604-1606
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	39
Issue number	11
DOIs	https://doi.org/10.1021/jo00924a042
State	Published - 1 May 1974
Externally published	Yes

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10.1021/jo00924a042

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title = "The Degenerate Rearrangement of the Benzo[6,7]bicyclo[3.2.2]nonatrienyl Anion. Relative Stability of a Benzylic and an Allylic Anion",

abstract = "The benzo-6,7-bicyclo[3.2.2]nonatrienyl anion undergoes a facile degenerate 7-carbon scrambling detected using 13C nmr techniques; the rearrangement has been used to probe relative anion stabilities.",

author = "Moncur, \{M. V.\} and Grutzner, \{John B.\} and A. Eisenstadt",

year = "1974",

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doi = "10.1021/jo00924a042",

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AU - Moncur, M. V.

AU - Grutzner, John B.

AU - Eisenstadt, A.

PY - 1974/5/1

Y1 - 1974/5/1

N2 - The benzo-6,7-bicyclo[3.2.2]nonatrienyl anion undergoes a facile degenerate 7-carbon scrambling detected using 13C nmr techniques; the rearrangement has been used to probe relative anion stabilities.

AB - The benzo-6,7-bicyclo[3.2.2]nonatrienyl anion undergoes a facile degenerate 7-carbon scrambling detected using 13C nmr techniques; the rearrangement has been used to probe relative anion stabilities.

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DO - 10.1021/jo00924a042

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JF - Journal of Organic Chemistry

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ER -

The Degenerate Rearrangement of the Benzo[6,7]bicyclo[3.2.2]nonatrienyl Anion. Relative Stability of a Benzylic and an Allylic Anion

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