The Ambident Nucleophilic Center. Stereochemical Consequences of HOMO‐LUMO and HOMO‐HOMO Dominant Processes

Keyphrases

• Acetonitrile 100%
• Dominant Processes 100%
• Nucleophilic 100%
• HOMO-LUMO 100%
• Stereochemical Hypothesis 100%
• Anions 80%
• Pyrrole 60%
• Quinoline 60%
• Pyridine 40%
• Carbazole 40%
• Nucleophile 40%
• Electron Pairing 40%
• Transition Structure 40%
• Electrophilic Reagents 40%
• Non-bonding Orbitals 40%
• Retardation 20%
• Low-lying 20%
• Methyl 20%
• Molecular Orbital 20%
• Stereoelectronic Effects 20%
• Rate Retardation 20%
• Frontier Molecular Orbitals 20%
• Molecular Orbital Interactions 20%

Chemistry

• Acetonitrile 100%
• Pyrrole 60%
• Carbazole 40%
• Electrophilic Reagent 40%
• Nucleophile 40%
• Donor 20%
• Lowest Unoccupied Molecular Orbital 20%
• Molecular Orbital 20%
• Stereoelectronic Effect 20%
• Frontier Orbital 20%
• Cation 20%

Pharmacology, Toxicology and Pharmaceutical Science

• Acetonitrile 100%
• Pyrrole 60%
• Nucleophile 40%
• Molecular Orbital 40%
• Carbazole Derivative 40%
• Chlordiazepoxide 20%