Synthesis, structural and X-ray absorption spectroscopy of (Pb                         x                         Bi                         1-x                         ).TiO                         3                          borosilicate glass and glass ceramics

Abhishek Madheshiya; Chandkiram Gautam; Subodh Kumar

doi:10.1016/j.jascer.2017.05.003

Synthesis, structural and X-ray absorption spectroscopy of (Pb _x Bi _1-x ).TiO ₃ borosilicate glass and glass ceramics

Abhishek Madheshiya
, Chandkiram Gautam
, Subodh Kumar

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Two series of glasses were synthesized by conventional rapid melt-quench method for different glass systems 55[(Pb _x Bi _1-x ).TiO ₃ ]-44[2SiO ₂ B ₂ O ₃ ] and 65[(Pb _x Bi _1-x ).TiO ₃ ]-34[2SiO ₂ B ₂ O ₃ ] doped with 1 mole percent of La ₂ O ₃ . X-ray diffraction study of synthesized glass sample shows amorphous nature while the glass ceramic sample revealed a cubic crystal structure due to devitrification of the glass as major crystalline phase of bismuth titanium oxide. X-ray absorption spectroscopy measurements in transmission mode were carried out and confirm the maximum value of absorption coefficient, 3.05 at energy 13450 eV for lead free glass ceramic sample. Scanning electron microscopy and contact angle measurements were also performed to explain the surface morphology. Energy dispersive X-ray analysis confirmed the presence of grains of bismuth titanium oxide and its elemental analysis with O, Ti, Si, Bi nanoparticles. The inclusions of La ₂ O ₃ results in development of well interconnected crystallites were formed as major phase of bismuth titanium oxide.

Original language	English
Pages (from-to)	276-283
Number of pages	8
Journal	Journal of Asian Ceramic Societies
Volume	5
Issue number	3
DOIs	https://doi.org/10.1016/j.jascer.2017.05.003
State	Published - Sep 2017
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2017 The Ceramic Society of Japan and the Korean Ceramic Society

Funding

The authors are gratefully acknowledged to the Uttar Pradesh Council of Science and Technology (UPCST), Lucknow (India), for the financial support under the ‘Young Scientist Scheme’ with a Major Research Project No. CSTT/YSS/D-3913. Authors are also acknowledged to the Council of Scientific and Industrial Research-Human Resource Development Group, CSIR Complex, Pusa, New Delhi (India) for financial support under the ‘Senior Research Fellowship’ with Ack. No. 124250/2K15/1—EMR-I. Authors are very much thankful to Prof. S. N. Jha, Department of Atomic Energy, Raja Ramanna Centre for Advanced Technology, Indore (India), who has kindly agreed to XAS measurement facilities. The authors are gratefully acknowledged to the Uttar Pradesh Council of Science and Technology (UPCST), Lucknow (India) , for the financial support under the ‘Young Scientist Scheme’ with a Major Research Project No. CSTT/YSS/D-3913. Authors are also acknowledged to the Council of Scientific and Industrial Research-Human Resource Development Group, CSIR Complex, Pusa, New Delhi (India) for financial support under the ‘Senior Research Fellowship’ with Ack. No. 124250/2K15/1—EMR-I. Authors are very much thankful to Prof. S. N. Jha, Department of Atomic Energy, Raja Ramanna Centre for Advanced Technology, Indore (India), who has kindly agreed to XAS measurement facilities.

Funders	Funder number
CSIR Complex
Council of Scientific and Industrial Research-Human Resource Development Group
Raja Ramanna Centre for Advanced Technology, Indore (India)
Human Resource Development Group
Council of Scientific and Industrial Research, India	124250/2K15/1—EMR-I
Department of Atomic Energy, Government of India
Uttarakhand State Council for Science and Technology
Council of Science and Technology, U.P.	CSTT/YSS/D-3913

Keywords

(Pb,Bi).TiO glasses
Contact angle
Density
EDAX
Molar volume
SEM
X-ray absorption spectroscopy
XRD

Access to Document

10.1016/j.jascer.2017.05.003

Cite this

Madheshiya, A., Gautam, C., & Kumar, S. (2017). Synthesis, structural and X-ray absorption spectroscopy of (Pb _x Bi _1-x ).TiO ₃ borosilicate glass and glass ceramics Journal of Asian Ceramic Societies, 5(3), 276-283. https://doi.org/10.1016/j.jascer.2017.05.003

Madheshiya, Abhishek ; Gautam, Chandkiram ; Kumar, Subodh. / Synthesis, structural and X-ray absorption spectroscopy of (Pb _x Bi _1-x ).TiO ₃ borosilicate glass and glass ceramics In: Journal of Asian Ceramic Societies. 2017 ; Vol. 5, No. 3. pp. 276-283.

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title = " Synthesis, structural and X-ray absorption spectroscopy of (Pb x Bi 1-x ).TiO 3 borosilicate glass and glass ceramics ",

abstract = " Two series of glasses were synthesized by conventional rapid melt-quench method for different glass systems 55[(Pb x Bi 1-x ).TiO 3 ]-44[2SiO 2 B 2 O 3 ] and 65[(Pb x Bi 1-x ).TiO 3 ]-34[2SiO 2 B 2 O 3 ] doped with 1 mole percent of La 2 O 3 . X-ray diffraction study of synthesized glass sample shows amorphous nature while the glass ceramic sample revealed a cubic crystal structure due to devitrification of the glass as major crystalline phase of bismuth titanium oxide. X-ray absorption spectroscopy measurements in transmission mode were carried out and confirm the maximum value of absorption coefficient, 3.05 at energy 13450 eV for lead free glass ceramic sample. Scanning electron microscopy and contact angle measurements were also performed to explain the surface morphology. Energy dispersive X-ray analysis confirmed the presence of grains of bismuth titanium oxide and its elemental analysis with O, Ti, Si, Bi nanoparticles. The inclusions of La 2 O 3 results in development of well interconnected crystallites were formed as major phase of bismuth titanium oxide.",

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Madheshiya, A, Gautam, C & Kumar, S 2017, ' Synthesis, structural and X-ray absorption spectroscopy of (Pb _x Bi _1-x ).TiO ₃ borosilicate glass and glass ceramics ', Journal of Asian Ceramic Societies, vol. 5, no. 3, pp. 276-283. https://doi.org/10.1016/j.jascer.2017.05.003

Synthesis, structural and X-ray absorption spectroscopy of (Pb _x Bi _1-x ).TiO ₃ borosilicate glass and glass ceramics . / Madheshiya, Abhishek; Gautam, Chandkiram; Kumar, Subodh.
In: Journal of Asian Ceramic Societies, Vol. 5, No. 3, 09.2017, p. 276-283.

Research output: Contribution to journal › Article › peer-review

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Madheshiya A, Gautam C, Kumar S. Synthesis, structural and X-ray absorption spectroscopy of (Pb _x Bi _1-x ).TiO ₃ borosilicate glass and glass ceramics Journal of Asian Ceramic Societies. 2017 Sep;5(3):276-283. doi: 10.1016/j.jascer.2017.05.003