Synthesis of WO3 nanoparticles using a biopolymer as a template for electrocatalytic hydrogen evolution

Raman Ganesan, Aharon Gedanken

Research output: Contribution to journalArticlepeer-review

53 Scopus citations

Abstract

Tungsten trioxide nanoparticles were prepared by a simple approach using chitosan biopolymer as a template. These nanoparticles were characterized using x-ray diffraction, Raman spectroscopy, transmission electron microscopy and high resolution transmission electron microscopy. The average size of the WO 3 nanoparticles is 42 nm, and they intercalate a larger amount of hydrogen than tungsten trioxide, which is prepared without chitosan. The materials are tested for their electrocatalytic hydrogen evolution in a sulfuric acid medium, where WO3 nanoparticles show a fourfold higher activity than bulk tungsten trioxide.

Original languageEnglish
Article number025702
JournalNanotechnology
Volume19
Issue number2
DOIs
StatePublished - 16 Jan 2008

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