A procedure has been developed for the intercalation of pyrrole into nanocavities of a metal-organic coordination polymer, chromium terephthalate MIL-101, and oxidative polymerization of pyrrole has been accomplished. The new composite nanomaterial thus obtained, polypyrrole@MIL-101, has been characterized by the data of elemental analysis, X-ray powder diffraction, thermal analysis, and scanning electron microscopy. Its specific surface area has been estimated at 1700 m2/g according to Brunauer-Emmett-Teller.
Bibliographical noteFunding Information:
This study was performed under financial support by the Russian Foundation for Basic Research (project no. 14-03-00 141-a) and by the Council for Grants at the President of the Russian Federation for State Support of Leading Scientific Schools (project no. NSh-516-2014.3).