Synthesis of photolabile group protected anomeric acetals and its application in carbohydrate synthesis with the assistance of continuous flow photo-reactor

Varsha Tiwari; Vishnu Nayak Badavath; Adesh Kumar Singh; Jeyakumar Kandasamy

Synthesis of photolabile group protected anomeric acetals and its application in carbohydrate synthesis with the assistance of continuous flow photo-reactor

Varsha Tiwari
, Vishnu Nayak Badavath
, Adesh Kumar Singh
, Jeyakumar Kandasamy

Indian Institute of Technology Banaras Hindu University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Selective deprotection of photolabile anomeric 2-nitrobenzyl acetals was achieved using continuous flow photo-reactor (UV radiation at 355 nm) in methanol-water. Various protecting groups such as acetyl, benzyl, benzoyl, benzylidine, TBS, etc. were found to be highly stable during the photolysis.

Original language	English
Pages (from-to)	227-236
Number of pages	10
Journal	Journal of the Indian Chemical Society
Volume	97
Issue number	2
State	Published - Feb 2020
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2020 Scientific Publishers. All rights reserved.

Keywords

Anomeric acetals
Methanol
Photo-reactor
Photolabile protecting group
UV-radiation

Cite this

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title = "Synthesis of photolabile group protected anomeric acetals and its application in carbohydrate synthesis with the assistance of continuous flow photo-reactor",

abstract = "Selective deprotection of photolabile anomeric 2-nitrobenzyl acetals was achieved using continuous flow photo-reactor (UV radiation at 355 nm) in methanol-water. Various protecting groups such as acetyl, benzyl, benzoyl, benzylidine, TBS, etc. were found to be highly stable during the photolysis.",

keywords = "Anomeric acetals, Methanol, Photo-reactor, Photolabile protecting group, UV-radiation",

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volume = "97",

pages = "227--236",

journal = "Journal of the Indian Chemical Society",

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Synthesis of photolabile group protected anomeric acetals and its application in carbohydrate synthesis with the assistance of continuous flow photo-reactor. / Tiwari, Varsha; Badavath, Vishnu Nayak; Singh, Adesh Kumar et al.
In: Journal of the Indian Chemical Society, Vol. 97, No. 2, 02.2020, p. 227-236.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of photolabile group protected anomeric acetals and its application in carbohydrate synthesis with the assistance of continuous flow photo-reactor

AU - Tiwari, Varsha

AU - Badavath, Vishnu Nayak

AU - Singh, Adesh Kumar

AU - Kandasamy, Jeyakumar

PY - 2020/2

Y1 - 2020/2

N2 - Selective deprotection of photolabile anomeric 2-nitrobenzyl acetals was achieved using continuous flow photo-reactor (UV radiation at 355 nm) in methanol-water. Various protecting groups such as acetyl, benzyl, benzoyl, benzylidine, TBS, etc. were found to be highly stable during the photolysis.

AB - Selective deprotection of photolabile anomeric 2-nitrobenzyl acetals was achieved using continuous flow photo-reactor (UV radiation at 355 nm) in methanol-water. Various protecting groups such as acetyl, benzyl, benzoyl, benzylidine, TBS, etc. were found to be highly stable during the photolysis.

KW - Anomeric acetals

KW - Methanol

KW - Photo-reactor

KW - Photolabile protecting group

KW - UV-radiation

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AN - SCOPUS:85081572560

SN - 0019-4522

VL - 97

SP - 227

EP - 236

JO - Journal of the Indian Chemical Society

JF - Journal of the Indian Chemical Society

IS - 2

ER -

Synthesis of photolabile group protected anomeric acetals and its application in carbohydrate synthesis with the assistance of continuous flow photo-reactor

Abstract

Bibliographical note

Keywords

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