TY - JOUR
T1 - Synthesis of functionalized triphenylenes by selective ether cleavage with B-bromocatecholborane
AU - Kumar, Sandeep
AU - Manickam, M.
PY - 1998/8
Y1 - 1998/8
N2 - This paper presents an efficient synthetic procedure for the preparation of mono-, di- and trifunctionalized triphenylene derivatives starting from the readily available hexakis(pentyloxy)triphenylene by selective ether cleavages with B-bromocatecholborane (2-bromo-1,3,2-benzodioxaboroles). Functionalized triphenylene derivatives are the precursor molecules for the preparation of processible triphenylene discotic dimers, oligomers, polymers and networks.
AB - This paper presents an efficient synthetic procedure for the preparation of mono-, di- and trifunctionalized triphenylene derivatives starting from the readily available hexakis(pentyloxy)triphenylene by selective ether cleavages with B-bromocatecholborane (2-bromo-1,3,2-benzodioxaboroles). Functionalized triphenylene derivatives are the precursor molecules for the preparation of processible triphenylene discotic dimers, oligomers, polymers and networks.
KW - Discotic liquid crystals
KW - Functionalized triphenylene
KW - Hexakis(pentyloxy)tri-phenylene
KW - Selective ether cleavage
UR - http://www.scopus.com/inward/record.url?scp=0031853957&partnerID=8YFLogxK
U2 - 10.1055/s-1998-2133
DO - 10.1055/s-1998-2133
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AN - SCOPUS:0031853957
SN - 0039-7881
SP - 1119
EP - 1122
JO - Synthesis
JF - Synthesis
IS - 8
ER -