Synthesis and structure of the coordination polymer [Li 5/3 H 1/3 (H 4 chhc)]

S. B. Aliev, D. G. Samsonenko, V. P. Fedin

Research output: Contribution to journalArticlepeer-review

Abstract

The coordination polymer of the composition [ Li 5/3 H 1/3 (H 4 chhc)] was synthesized by the reaction of lithium hydroxide monohydrate with 1,2,3,4,5,6-cyclohexanehexacarboxylic acid (H 6 chhc) at 100°C in a 1,4-dioxane - methanol mixture. The structure of this compound was determined by X-ray crystallography and confirmed by IR spectroscopy, as well as by thermo- gravimetric and elemental analysis. The coordination polymer has a structure of a 3D metal- organic framework built from lithium cations and H 4 chhc 2- anions.

Original languageEnglish
Pages (from-to)997-1000
Number of pages4
JournalRussian Chemical Bulletin
Volume63
Issue number4
DOIs
StatePublished - Apr 2014
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2014 Springer Science+Business Media, Inc.

Keywords

  • Coordination polymers
  • Cyclohexanehexa-carboxylic acid
  • Lithium
  • Metal-organic frameworks
  • X-ray crystallography

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