Synthesis and reactivity of chiral organometallic phosphonium salts

Patrice Pinsard; Jean Paul Lellouche; Jean Pierre Beaucoufi; René Grée

doi:10.1016/s0040-4039(00)88745-6

Synthesis and reactivity of chiral organometallic phosphonium salts

Patrice Pinsard
, Jean Paul Lellouche
, Jean Pierre Beaucoufi
, René Grée

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A short and efficient synthesis of the two enantiomeric iron-complexed phosphonium salts (+)-1 and (-)-2 is described. Upon reaction with the chiral formyloxirane 3, the corresponding chiral ylides exhibit quite different reactivities.

Original language	English
Pages (from-to)	1137-1140
Number of pages	4
Journal	Tetrahedron Letters
Volume	31
Issue number	8
DOIs	https://doi.org/10.1016/s0040-4039(00)88745-6
State	Published - 1990
Externally published	Yes

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title = "Synthesis and reactivity of chiral organometallic phosphonium salts",

abstract = "A short and efficient synthesis of the two enantiomeric iron-complexed phosphonium salts (+)-1 and (-)-2 is described. Upon reaction with the chiral formyloxirane 3, the corresponding chiral ylides exhibit quite different reactivities.",

author = "Patrice Pinsard and Lellouche, \{Jean Paul\} and Beaucoufi, \{Jean Pierre\} and Ren{\'e} Gr{\'e}e",

year = "1990",

doi = "10.1016/s0040-4039(00)88745-6",

language = "אנגלית",

volume = "31",

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journal = "Tetrahedron Letters",

issn = "0040-4039",

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T1 - Synthesis and reactivity of chiral organometallic phosphonium salts

AU - Pinsard, Patrice

AU - Lellouche, Jean Paul

AU - Beaucoufi, Jean Pierre

AU - Grée, René

PY - 1990

Y1 - 1990

N2 - A short and efficient synthesis of the two enantiomeric iron-complexed phosphonium salts (+)-1 and (-)-2 is described. Upon reaction with the chiral formyloxirane 3, the corresponding chiral ylides exhibit quite different reactivities.

AB - A short and efficient synthesis of the two enantiomeric iron-complexed phosphonium salts (+)-1 and (-)-2 is described. Upon reaction with the chiral formyloxirane 3, the corresponding chiral ylides exhibit quite different reactivities.

UR - https://www.scopus.com/pages/publications/0025186565

U2 - 10.1016/s0040-4039(00)88745-6

DO - 10.1016/s0040-4039(00)88745-6

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AN - SCOPUS:0025186565

SN - 0040-4039

VL - 31

SP - 1137

EP - 1140

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 8

ER -

Synthesis and reactivity of chiral organometallic phosphonium salts

Abstract

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