TY - JOUR
T1 - Synthesis and properties of 1,2,2,6,6-pentamethyl-3,5-dimethylene-4-piperidone
AU - Belostotskii, A. M.
AU - Shapiro, A. B.
PY - 1984/7
Y1 - 1984/7
N2 - 1,2,2,6,6-Pentamethyl-3,5-dimethylene-4-piperidone was synthesized, whereas analogous compounds in the 4-piperidone series could not be isolated. An unusual reaction of the compound obtained with primary aliphatic amines, consisting of successive addition of the amine at the C=C bonds, with a possible formation of an intermediate bicyclic adduct and further elimination of methylamine, was detected.
AB - 1,2,2,6,6-Pentamethyl-3,5-dimethylene-4-piperidone was synthesized, whereas analogous compounds in the 4-piperidone series could not be isolated. An unusual reaction of the compound obtained with primary aliphatic amines, consisting of successive addition of the amine at the C=C bonds, with a possible formation of an intermediate bicyclic adduct and further elimination of methylamine, was detected.
UR - http://www.scopus.com/inward/record.url?scp=34250117368&partnerID=8YFLogxK
U2 - 10.1007/BF00506967
DO - 10.1007/BF00506967
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SN - 0009-3122
VL - 20
SP - 761
EP - 766
JO - Chemistry of Heterocyclic Compounds
JF - Chemistry of Heterocyclic Compounds
IS - 7
ER -