Synthesis and crystal structure of the porous metal-organic coordination polymer [Zn4(Ndc)4(Oxdz)2] · 2H 2O

S. B. Aliev; D. G. Samsonenko; V. P. Fedin

doi:10.1134/s1070328413020012

Synthesis and crystal structure of the porous metal-organic coordination polymer [Zn₄(Ndc)₄(Oxdz)₂] · 2H ₂O

S. B. Aliev, D. G. Samsonenko, V. P. Fedin

Research output: Contribution to journal › Article › peer-review

Abstract

New metal-organic coordination polymer [Zn₄(Ndc) ₄(Oxdz)₂] · 2H₂O (H2Ndc = 2,6-naphthalenedicarboxylic acid, Oxdz = 1,3,4-oxadiazole) was prepared by heating a solution of zinc nitrate, naphthalenedicarboxylic acid, and 4-aminotriazole in DMF. Of particular interest is the in situ transformation of 4-aminotriazole into 1,3,4-oxadiazole. The structure and the composition of the obtained compounds were established by X-ray diffraction, IR spectroscopy, and elemental analysis. The metal-organic framework is electrically neutral and forms a channel structure with the pore diameter of 9 Å.

Original language	English
Pages (from-to)	157-160
Number of pages	4
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	39
Issue number	2
DOIs	https://doi.org/10.1134/s1070328413020012
State	Published - 2013
Externally published	Yes

Bibliographical note

Funding Information:
ACKNOWLEDGMENTS This work was supported by the Program 5.6.1 of the Division of Chemistry and Materials Science of the RAS and by the Russian Foundation for Basic Research (projects nos. 11 03 00112 and 11 03 12038).

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title = "Synthesis and crystal structure of the porous metal-organic coordination polymer [Zn4(Ndc)4(Oxdz)2] · 2H 2O",

abstract = "New metal-organic coordination polymer [Zn4(Ndc) 4(Oxdz)2] · 2H2O (H2Ndc = 2,6-naphthalenedicarboxylic acid, Oxdz = 1,3,4-oxadiazole) was prepared by heating a solution of zinc nitrate, naphthalenedicarboxylic acid, and 4-aminotriazole in DMF. Of particular interest is the in situ transformation of 4-aminotriazole into 1,3,4-oxadiazole. The structure and the composition of the obtained compounds were established by X-ray diffraction, IR spectroscopy, and elemental analysis. The metal-organic framework is electrically neutral and forms a channel structure with the pore diameter of 9 {\AA}.",

author = "Aliev, {S. B.} and Samsonenko, {D. G.} and Fedin, {V. P.}",

note = "Funding Information: ACKNOWLEDGMENTS This work was supported by the Program 5.6.1 of the Division of Chemistry and Materials Science of the RAS and by the Russian Foundation for Basic Research (projects nos. 11 03 00112 and 11 03 12038).",

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doi = "10.1134/s1070328413020012",

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AU - Samsonenko, D. G.

AU - Fedin, V. P.

N1 - Funding Information: ACKNOWLEDGMENTS This work was supported by the Program 5.6.1 of the Division of Chemistry and Materials Science of the RAS and by the Russian Foundation for Basic Research (projects nos. 11 03 00112 and 11 03 12038).

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AB - New metal-organic coordination polymer [Zn4(Ndc) 4(Oxdz)2] · 2H2O (H2Ndc = 2,6-naphthalenedicarboxylic acid, Oxdz = 1,3,4-oxadiazole) was prepared by heating a solution of zinc nitrate, naphthalenedicarboxylic acid, and 4-aminotriazole in DMF. Of particular interest is the in situ transformation of 4-aminotriazole into 1,3,4-oxadiazole. The structure and the composition of the obtained compounds were established by X-ray diffraction, IR spectroscopy, and elemental analysis. The metal-organic framework is electrically neutral and forms a channel structure with the pore diameter of 9 Å.

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Synthesis and crystal structure of the porous metal-organic coordination polymer [Zn₄(Ndc)₄(Oxdz)₂] · 2H ₂O

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