Abstract
The synthesis and reactivity of diallenic α-disulfones and diallenic sulfinyl sulfones are described. Both types of compound exhibit enhanced reactivity relative to their saturated counterparts, and react spontaneously at low temperature, upon preparation, to yield novel and functionalized bicyclic products. Possible mechanisms for their multi-step rearrangements are suggested.
Original language | English |
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Pages (from-to) | 6713-6716 |
Number of pages | 4 |
Journal | Tetrahedron Letters |
Volume | 48 |
Issue number | 38 |
DOIs | |
State | Published - 17 Sep 2007 |
Bibliographical note
Funding Information:This work was supported by a grant from the Israel Science Foundation (Grant No. 919-05).
Funding
This work was supported by a grant from the Israel Science Foundation (Grant No. 919-05).
Funders | Funder number |
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Israel Science Foundation | 919-05 |
Keywords
- Allenes
- Sulfinyl sulfones
- Tandem reaction
- α-Disulfones
- γ-Sultines
- γ-Sultones