Switchable p-n gas response for 3D-hierarchical NiFe2O4 porous microspheres for highly selective and sensitive toluene gas sensors

K. Karuppasamy, Bharat Sharma, Dhanasekaran Vikraman, Eun Bee Jo, P. Sivakumar, Hyun Seok Kim

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

Rationally designed gas sensing materials have become essential for modern efficient gas sensor with enhanced performance. This study designed and prepared ordered porous, three-dimensional hierarchical NiFe2O4 (NFO) nanoarchitectures for highly selective and sensitive toluene sensors. Two hierarchical NFO nanostructures including nanospheres and microsphere were fabricated by facile hydrothermal (NFO-Hy) and temperature-programmed calcination (NFO-550), respectively. Physicochemical characterization confirmed structure, composition, and morphology for the as-prepared materials. Nitrogen adsorption-desorption revealed improved surface area and porous properties for NFO-550 compared with NFO-Hy sensing materials, and the NFO-550 sensor achieved the maximum response 5.65 higher than NFO-Hy at optimal operating temperature. Primary analyses for carcinogenic analyte detection suggest NFO as a gas-sensitive material to be potential applicants for real-world toluene gas sensing applications.

Original languageEnglish
Article number161281
JournalJournal of Alloys and Compounds
Volume886
DOIs
StatePublished - 15 Dec 2021
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2021 Elsevier B.V.

Funding

This work was supported by the Mid-career Researcher Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (No. 2019R1A2C2086747 ).

FundersFunder number
Ministry of Science, ICT and Future Planning2019R1A2C2086747
National Research Foundation of Korea

    Keywords

    • Microsphere
    • Nickel iron oxide
    • Textural properties
    • Toluene sensor
    • Toxic analyte

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