Surface transfer doping of diamond with a molecular heterojunction

D. P. Langley; Y. Smets; C. B. Stark; M. T. Edmonds; A. Tadich; K. J. Rietwyk; A. Schenk; M. Wanke; Q. H. Wu; P. J. Barnard; L. Ley; C. I. Pakes

doi:10.1063/1.3676445

Surface transfer doping of diamond with a molecular heterojunction

D. P. Langley, Y. Smets, C. B. Stark, M. T. Edmonds, A. Tadich, K. J. Rietwyk, A. Schenk, M. Wanke, Q. H. Wu, P. J. Barnard, L. Ley, C. I. Pakes

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Surface conductivity and C1s core level measurements were employed to show that surface transfer doping of hydrogen-terminated diamond C(100) can be achieved with a molecular heterojunction formed with C ₆₀F ₄₈ and an intralayer of zinc-tetraphenylporphyrin. Measurement of the shift in the diamond Fermi energy shows that the zinc-tetraphenylporphyrin (ZnTPP) layer modifies the C ₆₀F ₄₈-diamond interaction, modulating the extent of charge transfer between the diamond and the fluorofullerene. In contrast to the case of C ₆₀F ₄₈ acceptors, the presence of a ZnTPP layer prevents the formation of air-induced surface conductivity, showing that the intralayer acts to selectively separate these two doping channels.

Original language	English
Article number	032103
Journal	Applied Physics Letters
Volume	100
Issue number	3
DOIs	https://doi.org/10.1063/1.3676445
State	Published - 16 Jan 2012
Externally published	Yes

Bibliographical note

Funding Information:
We acknowledge financial support of the Australian Research Council.

Access to Document

10.1063/1.3676445

Cite this

@article{c19a38c6682a4e30bb9f069459dce905,

title = "Surface transfer doping of diamond with a molecular heterojunction",

abstract = "Surface conductivity and C1s core level measurements were employed to show that surface transfer doping of hydrogen-terminated diamond C(100) can be achieved with a molecular heterojunction formed with C 60F 48 and an intralayer of zinc-tetraphenylporphyrin. Measurement of the shift in the diamond Fermi energy shows that the zinc-tetraphenylporphyrin (ZnTPP) layer modifies the C 60F 48-diamond interaction, modulating the extent of charge transfer between the diamond and the fluorofullerene. In contrast to the case of C 60F 48 acceptors, the presence of a ZnTPP layer prevents the formation of air-induced surface conductivity, showing that the intralayer acts to selectively separate these two doping channels.",

author = "Langley, {D. P.} and Y. Smets and Stark, {C. B.} and Edmonds, {M. T.} and A. Tadich and Rietwyk, {K. J.} and A. Schenk and M. Wanke and Wu, {Q. H.} and Barnard, {P. J.} and L. Ley and Pakes, {C. I.}",

note = "Funding Information: We acknowledge financial support of the Australian Research Council.",

year = "2012",

month = jan,

day = "16",

doi = "10.1063/1.3676445",

language = "אנגלית",

volume = "100",

journal = "Applied Physics Letters",

issn = "0003-6951",

publisher = "American Institute of Physics",

number = "3",

}

TY - JOUR

T1 - Surface transfer doping of diamond with a molecular heterojunction

AU - Langley, D. P.

AU - Smets, Y.

AU - Stark, C. B.

AU - Edmonds, M. T.

AU - Tadich, A.

AU - Rietwyk, K. J.

AU - Schenk, A.

AU - Wanke, M.

AU - Wu, Q. H.

AU - Barnard, P. J.

AU - Ley, L.

AU - Pakes, C. I.

N1 - Funding Information: We acknowledge financial support of the Australian Research Council.

PY - 2012/1/16

Y1 - 2012/1/16

N2 - Surface conductivity and C1s core level measurements were employed to show that surface transfer doping of hydrogen-terminated diamond C(100) can be achieved with a molecular heterojunction formed with C 60F 48 and an intralayer of zinc-tetraphenylporphyrin. Measurement of the shift in the diamond Fermi energy shows that the zinc-tetraphenylporphyrin (ZnTPP) layer modifies the C 60F 48-diamond interaction, modulating the extent of charge transfer between the diamond and the fluorofullerene. In contrast to the case of C 60F 48 acceptors, the presence of a ZnTPP layer prevents the formation of air-induced surface conductivity, showing that the intralayer acts to selectively separate these two doping channels.

AB - Surface conductivity and C1s core level measurements were employed to show that surface transfer doping of hydrogen-terminated diamond C(100) can be achieved with a molecular heterojunction formed with C 60F 48 and an intralayer of zinc-tetraphenylporphyrin. Measurement of the shift in the diamond Fermi energy shows that the zinc-tetraphenylporphyrin (ZnTPP) layer modifies the C 60F 48-diamond interaction, modulating the extent of charge transfer between the diamond and the fluorofullerene. In contrast to the case of C 60F 48 acceptors, the presence of a ZnTPP layer prevents the formation of air-induced surface conductivity, showing that the intralayer acts to selectively separate these two doping channels.

UR - http://www.scopus.com/inward/record.url?scp=84856459432&partnerID=8YFLogxK

U2 - 10.1063/1.3676445

DO - 10.1063/1.3676445

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:84856459432

SN - 0003-6951

VL - 100

JO - Applied Physics Letters

JF - Applied Physics Letters

IS - 3

M1 - 032103

ER -

Surface transfer doping of diamond with a molecular heterojunction

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Cite this