Surface passivation of polycrystalline, chalcogenide based photovoltaic cells

David Cahen, Rommel Noufi

Research output: Contribution to journalArticlepeer-review

53 Scopus citations

Abstract

We present a summary of our defect chemical microscopic model for the effect that annealing in air or oxygen has on CuInSe2 and CdTe-based polycrystalline thin film solar cells and explain its generalization to other chalcogenide-based semiconductor devices. The summary includes a hypothesis for specific O2 (molecule) and surface interaction. From the point of view of device performance, the model provides a specific chemical explanation for the conclusions obtained from device analyses that the performance of the present generation of polycrystalline cells of this type is mainly limited by recombination at grain surfaces and boundaries.

Original languageEnglish
Pages (from-to)53-59
Number of pages7
JournalSolar Cells
Volume30
Issue number1-4
DOIs
StatePublished - May 1991
Externally publishedYes

Funding

D. C. thanks the Israel National Council for Research and Development, through the KFA Julich (Germany) for practical support. Work at SERI is supported under U.S. DOE contract CE-AC02-CH0093. We thank Dr. H. Dittrich, Institute for Physics and Electronics, University of Stuttgart for the PBC argument.

FundersFunder number
Israel National Council for Research and Development
U.S. Department of EnergyCE-AC02-CH0093
Spine Education and Research Institute

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