Surface-initiated polymerization on self-assembled monolayers: Effect of reaction conditions

Ursula Schmelmer; Anne Paul; Alexander Küller; Rainer Jordan; Armin Gölzhäuser; Michael Grunze; Abraham Ulman

doi:10.1002/masy.200451318

Surface-initiated polymerization on self-assembled monolayers: Effect of reaction conditions

Ursula Schmelmer
, Anne Paul
, Alexander Küller
, Rainer Jordan
, Armin Gölzhäuser
, Michael Grunze
, Abraham Ulman

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Self-assembled monolayers of 4′-nitro-4-mercaptobiphenyl were modified by electron beam irradiation and diazotization to create a surface-bond asymmetric azo initiator for the surface-initiated polymerization (SIP). The effect of different reaction conditions upon the thermally and photochemical initiated SIP was investigated.

Original language	English
Pages (from-to)	223-230
Number of pages	8
Journal	Macromolecular Symposia
Volume	217
DOIs	https://doi.org/10.1002/masy.200451318
State	Published - Oct 2004
Externally published	Yes

Keywords

Azo initiator
Decomposition
Polymer brushes
Self-assembled monolayers
Surface-initiated polymerization

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10.1002/masy.200451318

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abstract = "Self-assembled monolayers of 4′-nitro-4-mercaptobiphenyl were modified by electron beam irradiation and diazotization to create a surface-bond asymmetric azo initiator for the surface-initiated polymerization (SIP). The effect of different reaction conditions upon the thermally and photochemical initiated SIP was investigated.",

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AU - Küller, Alexander

AU - Jordan, Rainer

AU - Gölzhäuser, Armin

AU - Grunze, Michael

AU - Ulman, Abraham

PY - 2004/10

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AB - Self-assembled monolayers of 4′-nitro-4-mercaptobiphenyl were modified by electron beam irradiation and diazotization to create a surface-bond asymmetric azo initiator for the surface-initiated polymerization (SIP). The effect of different reaction conditions upon the thermally and photochemical initiated SIP was investigated.

KW - Azo initiator

KW - Decomposition

KW - Polymer brushes

KW - Self-assembled monolayers

KW - Surface-initiated polymerization

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Surface-initiated polymerization on self-assembled monolayers: Effect of reaction conditions

Abstract

Keywords

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