Surface immobilization of an organo-iridium complex through a carbon-metal bond

Anna Razgon; Mitchell R. Anstey; Neal A. Yakelis; Robert G. Bergman; Chaim N. Sukenik

doi:10.1016/j.ica.2011.04.042

Surface immobilization of an organo-iridium complex through a carbon-metal bond

Anna Razgon, Mitchell R. Anstey, Neal A. Yakelis, Robert G. Bergman, Chaim N. Sukenik

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A new approach to the immobilization of organometallic complexes to monolayer surfaces is demonstrated using aldehyde-terminated self-assembled monolayers and a Cp^Ir complex. The iridium complex is anchored to the surface by direct attachment of the metal to the carbon chain of the monolayer film.

Original language	English
Pages (from-to)	305-307
Number of pages	3
Journal	Inorganica Chimica Acta
Volume	375
Issue number	1
DOIs	https://doi.org/10.1016/j.ica.2011.04.042
State	Published - 1 Sep 2011

Bibliographical note

Funding Information:
We thank the US Israel Binational Science Foundation for support of this work. R.G.B. and M.R.A. acknowledge partial support by the Director, Office of Energy Research, Office of Basic Energy Sciences, Chemical Sciences Division, of the US Department of Energy under Contract No. DE-AC03-7600098. C.N.S. acknowledges support of the Edward and Judith Steinberg Chair in Nanotechnology.

Funding

We thank the US Israel Binational Science Foundation for support of this work. R.G.B. and M.R.A. acknowledge partial support by the Director, Office of Energy Research, Office of Basic Energy Sciences, Chemical Sciences Division, of the US Department of Energy under Contract No. DE-AC03-7600098. C.N.S. acknowledges support of the Edward and Judith Steinberg Chair in Nanotechnology.

Funders	Funder number
Office of Energy Research
U.S. Department of Energy	DE-AC03-7600098
Basic Energy Sciences
United States-Israel Binational Science Foundation

Keywords

Metal-carbon bond
Organo-iridium chemistry
Self-assembled monolayers
Surface-anchored organometallic

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10.1016/j.ica.2011.04.042

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title = "Surface immobilization of an organo-iridium complex through a carbon-metal bond",

abstract = "A new approach to the immobilization of organometallic complexes to monolayer surfaces is demonstrated using aldehyde-terminated self-assembled monolayers and a CpIr complex. The iridium complex is anchored to the surface by direct attachment of the metal to the carbon chain of the monolayer film.",

keywords = "Metal-carbon bond, Organo-iridium chemistry, Self-assembled monolayers, Surface-anchored organometallic",

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AU - Bergman, Robert G.

AU - Sukenik, Chaim N.

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Surface immobilization of an organo-iridium complex through a carbon-metal bond

Abstract

Bibliographical note

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Keywords

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