Suppression of excluded-volume exponents in shear flow of dilute polymer solutions

Yitzhak Rabin, Kyozi Kawasaki

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

The analogy between polymer and binary critical fluid dynamics in simple shear flow is used to construct a renormalization-group analysis of the scaling exponent for the end-to-end distance of an isolated long polymer chain in a good solvent undergoing strong shear flow. The shear flow induces a crossover from the usual fixed point with the good solvent Flory exponent to a new, strong shear fixed point with the classical exponent =(1/2. Based on the blob picture we argue that the dynamic exponent z is not affected by the flow and remains at its zero shear, z=3 value. Experimentally observable consequences of this result are also discussed.

Original languageEnglish
Pages (from-to)2281-2284
Number of pages4
JournalPhysical Review Letters
Volume62
Issue number19
DOIs
StatePublished - 1989
Externally publishedYes

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