Superoxide-, tert-Butoxide-, and Hydroxide-Mediated Autoxidation of 3-Oxo-Δ4 Steroids in Aprotic Media

Aryeh A. Frimer; Pessia Gilinsky-Sharon; Judith Hameiri; Gladis Aljadeff

doi:10.1021/jo00135a038

Superoxide-, tert-Butoxide-, and Hydroxide-Mediated Autoxidation of 3-Oxo-Δ⁴ Steroids in Aprotic Media

Aryeh A. Frimer, Pessia Gilinsky-Sharon, Judith Hameiri, Gladis Aljadeff

Department of Chemistry

Bar-Ilan University

Research output: Contribution to journal › Letter › peer-review

22 Scopus citations

Abstract

The course of the base-catalyzed autoxidation of 3-oxo-Δ⁴ steroids in aprotic media differs sharply both in yield and product distribution from that reported for protic solvents and involves the oxygenation of the kinetic dienolate.

Original language	English
Pages (from-to)	2818-2819
Number of pages	2
Journal	Journal of Organic Chemistry
Volume	47
Issue number	14
DOIs	https://doi.org/10.1021/jo00135a038
State	Published - 1982

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title = "Superoxide-, tert-Butoxide-, and Hydroxide-Mediated Autoxidation of 3-Oxo-Δ4 Steroids in Aprotic Media",

abstract = "The course of the base-catalyzed autoxidation of 3-oxo-Δ4 steroids in aprotic media differs sharply both in yield and product distribution from that reported for protic solvents and involves the oxygenation of the kinetic dienolate.",

author = "Frimer, {Aryeh A.} and Pessia Gilinsky-Sharon and Judith Hameiri and Gladis Aljadeff",

year = "1982",

doi = "10.1021/jo00135a038",

language = "אנגלית",

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journal = "Journal of Organic Chemistry",

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T1 - Superoxide-, tert-Butoxide-, and Hydroxide-Mediated Autoxidation of 3-Oxo-Δ4 Steroids in Aprotic Media

AU - Frimer, Aryeh A.

AU - Gilinsky-Sharon, Pessia

AU - Hameiri, Judith

AU - Aljadeff, Gladis

PY - 1982

Y1 - 1982

N2 - The course of the base-catalyzed autoxidation of 3-oxo-Δ4 steroids in aprotic media differs sharply both in yield and product distribution from that reported for protic solvents and involves the oxygenation of the kinetic dienolate.

AB - The course of the base-catalyzed autoxidation of 3-oxo-Δ4 steroids in aprotic media differs sharply both in yield and product distribution from that reported for protic solvents and involves the oxygenation of the kinetic dienolate.

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AN - SCOPUS:33845553350

SN - 0022-3263

VL - 47

SP - 2818

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 14

ER -

Superoxide-, tert-Butoxide-, and Hydroxide-Mediated Autoxidation of 3-Oxo-Δ⁴ Steroids in Aprotic Media

Abstract

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