Using deprotonated forms of tetradentate phenol amine ligands 2-((((1-methylbenzimidazol-2-yl)methyl)(pyridin-2-ylmethyl)amino)methyl)phenol (HL1), dinuclear vanadium(IV,V) complex of composition [(L1)2(VIVO)(µ-O)(VVO)](ClO4) (1) was synthesized and characterized by X–ray crystallography, UV–Vis, EPR and magnetic susceptibility measurements. Direct current (DC) variable-temperature magnetic susceptibility measurements on polycrystalline sample of 1 were carried out in the temperature range 1.8–300 K. Electron paramagnetic resonance and magnetic studies for 1 demonstrated the complete localization of the single 3d electron on one of vanadium ion and very weak antiferromagnetic interaction between the paramagnetic vanadium(IV) ions in the crystal lattice. The cyclic voltammogram observed with 1, revealed one oxidation process which is tentatively assigned to VIVVV/V2V. [(L1)2(VVO)2(µ-O)](ClO4)2 (2.2.5CH2Cl2) has been synthesized chemically from 1 and were thoroughly characterized by X–ray crystallography, UV–Vis, 51V NMR and IR measurements.
|Journal||Journal of Molecular Structure|
|State||Published - 5 Dec 2022|
Bibliographical noteFunding Information:
Authors thank Prof. R.N. Mukherjee for using the lab facilities at IIT Kanpur. Authors also thank the CSIRC/ALHAMBRA supercomputing center of the Universidad de Granada for computational resources.
© 2022 Elsevier B.V.
- DFT calculations
- EPR spectroscopy
- Magnetic properties
- Redox properties
- Vanadium complexes
- X-ray diffraction