Stereoselective Michael additions of phosphorylated allyl carbanions - Synthesis of functionalized cyclopentylphosphonates and phosphane oxides

Keyphrases

• Stereoselectivity 100%
• Allyl 100%
• Carbanions 100%
• Michael Addition 100%
• Phosphane Oxides 100%
• Phosphonates 66%
• Tert-butyl 66%
• Phenyl 66%
• Dimethyl 66%
• Chloromethyl 66%
• Ketones 33%
• Open Chain 33%
• Stereochemistry 33%
• Diastereomers 33%
• Disubstituted 33%
• 1D NMR 33%
• Stereogenic Centers 33%
• 2D NMR Spectra 33%
• High Stereoselectivity 33%
• High Regioselectivity 33%
• Cyclopentane 33%
• Unsaturated Esters 33%
• Trimethylenemethane 33%
• Stereochemical Hypothesis 33%

Chemistry

• Michael Addition 100%
• Carbanion 100%
• Phosphane 100%
• Phosphonate 66%
• Stereoselectivity 66%
• Ketone 33%
• Stereochemistry 33%
• Diastereomer 33%
• Local-Density Approximation 33%
• Cyclopentane 33%
• Regioselectivity 33%
• 1D NMR Spectrum 33%
• 2D NMR Spectrum 33%