Stereochemistry. LXVII. Stereochemical Aspects of the Photochemical and Thermal Fragmentation of Cyclopropyl Azides

Alfred Hassner; Alan B. Levy; Edward E. McEntire; James E. Galle

doi:10.1021/jo00918a045

Stereochemistry. LXVII. Stereochemical Aspects of the Photochemical and Thermal Fragmentation of Cyclopropyl Azides

Alfred Hassner, Alan B. Levy, Edward E. McEntire, James E. Galle

University of Colorado Boulder

Research output: Contribution to journal › Letter › peer-review

14 Scopus citations

Abstract

Photolysis of cyclopropyl azides results in high yields of nitrile and olefin derived from fragmentation of the cyclopropane ring in contrast to their thermal decomposition which leads to 1-azetine and/or fragmentation; both the photochemical and the thermal fragmentation are stereospecific.

Original language	English
Pages (from-to)	585-586
Number of pages	2
Journal	Journal of Organic Chemistry
Volume	39
Issue number	4
DOIs	https://doi.org/10.1021/jo00918a045
State	Published - 1 Feb 1974
Externally published	Yes

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title = "Stereochemistry. LXVII. Stereochemical Aspects of the Photochemical and Thermal Fragmentation of Cyclopropyl Azides",

abstract = "Photolysis of cyclopropyl azides results in high yields of nitrile and olefin derived from fragmentation of the cyclopropane ring in contrast to their thermal decomposition which leads to 1-azetine and/or fragmentation; both the photochemical and the thermal fragmentation are stereospecific.",

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AU - Galle, James E.

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AB - Photolysis of cyclopropyl azides results in high yields of nitrile and olefin derived from fragmentation of the cyclopropane ring in contrast to their thermal decomposition which leads to 1-azetine and/or fragmentation; both the photochemical and the thermal fragmentation are stereospecific.

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Stereochemistry. LXVII. Stereochemical Aspects of the Photochemical and Thermal Fragmentation of Cyclopropyl Azides

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