Stannous chloride reduction of nitroalkenes in amines. Synthesis and cycloaddition of α-dialkylaminoaldoxime

Levi Gottlieb, Alfred Hassner, Hugo E. Gottlieb

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

α-Dialkylamino aldoximes 12 were prepared by stannous chloride reduction of nitroalkenes in amines. An intramolecular Michael addition- deoxygenation mechanism is suggested. α-Allylamino aldoxime underwent an efficient Intramolecular Oxime Olefin Cycloaddition (IOOC) giving 13.

Original languageEnglish
Pages (from-to)2445-2464
Number of pages20
JournalSynthetic Communications
Volume30
Issue number14
DOIs
StatePublished - 2000

Bibliographical note

Funding Information:
Acknowledgment: Support for this research by a grant from the Israel Research

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