Spectroscopic properties and energy levels of Yb3+ ion in huntite structure

A. V. Malakhovskii; A. L. Sukhachev; S. L. Gnatchenko; I. S. Kachur; V. G. Piryatinskaya; V. L. Temerov; A. S. Krylov; I. S. Edelman

doi:10.1016/j.jallcom.2008.08.045

Spectroscopic properties and energy levels of Yb³⁺ ion in huntite structure

A. V. Malakhovskii, A. L. Sukhachev, S. L. Gnatchenko, I. S. Kachur, V. G. Piryatinskaya, V. L. Temerov, A. S. Krylov, I. S. Edelman

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Temperature dependence of Yb³⁺ optical absorption spectrum has been studied in crystals Yb_xTm_1-xAl₃(BO₃)₄ (x = 0.1, 0.2 and 1) in the temperature range 1.7-293 K. The spectra of the crystals appeared to be practically identical for the studied ytterbium concentrations. Raman scattering spectrum of YbAl₃(BO₃)₄ crystal has been measured. Group theory analysis of the optical absorption spectra is made, and new energy structure of the ground and excited states of Yb³⁺ ion, based on the experimental data obtained, is presented. Transformation of the local environment of Yb³⁺ ion depending on temperature has been found out. Spectrum of luminescence has been calculated from the absorption spectrum by reciprocity method with the use of the proposed energy structure.

Original language	English
Pages (from-to)	64-69
Number of pages	6
Journal	Journal of Alloys and Compounds
Volume	476
Issue number	1-2
DOIs	https://doi.org/10.1016/j.jallcom.2008.08.045
State	Published - 12 May 2009
Externally published	Yes

Bibliographical note

Funding Information:
The work is supported by the Russian Foundation for Basic Researches, grant no. 07-02-00704. A.L. Sukhachev is thankful to Russian Science Support Foundation.

Funding

The work is supported by the Russian Foundation for Basic Researches, grant no. 07-02-00704. A.L. Sukhachev is thankful to Russian Science Support Foundation.

Funders	Funder number
Russian Foundation for Basic Research	07-02-00704

Keywords

Crystal growth
Electronic band structure
Insulators
Optical spectroscopy

Access to Document

10.1016/j.jallcom.2008.08.045

Cite this

@article{d257dd6282e04bbdb74ab940e3cd1bd8,

title = "Spectroscopic properties and energy levels of Yb3+ ion in huntite structure",

abstract = "Temperature dependence of Yb3+ optical absorption spectrum has been studied in crystals YbxTm1-xAl3(BO3)4 (x = 0.1, 0.2 and 1) in the temperature range 1.7-293 K. The spectra of the crystals appeared to be practically identical for the studied ytterbium concentrations. Raman scattering spectrum of YbAl3(BO3)4 crystal has been measured. Group theory analysis of the optical absorption spectra is made, and new energy structure of the ground and excited states of Yb3+ ion, based on the experimental data obtained, is presented. Transformation of the local environment of Yb3+ ion depending on temperature has been found out. Spectrum of luminescence has been calculated from the absorption spectrum by reciprocity method with the use of the proposed energy structure.",

keywords = "Crystal growth, Electronic band structure, Insulators, Optical spectroscopy",

author = "Malakhovskii, {A. V.} and Sukhachev, {A. L.} and Gnatchenko, {S. L.} and Kachur, {I. S.} and Piryatinskaya, {V. G.} and Temerov, {V. L.} and Krylov, {A. S.} and Edelman, {I. S.}",

note = "Funding Information: The work is supported by the Russian Foundation for Basic Researches, grant no. 07-02-00704. A.L. Sukhachev is thankful to Russian Science Support Foundation. ",

year = "2009",

month = may,

day = "12",

doi = "10.1016/j.jallcom.2008.08.045",

language = "אנגלית",

volume = "476",

pages = "64--69",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier B.V.",

number = "1-2",

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TY - JOUR

T1 - Spectroscopic properties and energy levels of Yb3+ ion in huntite structure

AU - Malakhovskii, A. V.

AU - Sukhachev, A. L.

AU - Gnatchenko, S. L.

AU - Kachur, I. S.

AU - Piryatinskaya, V. G.

AU - Temerov, V. L.

AU - Krylov, A. S.

AU - Edelman, I. S.

N1 - Funding Information: The work is supported by the Russian Foundation for Basic Researches, grant no. 07-02-00704. A.L. Sukhachev is thankful to Russian Science Support Foundation.

PY - 2009/5/12

Y1 - 2009/5/12

N2 - Temperature dependence of Yb3+ optical absorption spectrum has been studied in crystals YbxTm1-xAl3(BO3)4 (x = 0.1, 0.2 and 1) in the temperature range 1.7-293 K. The spectra of the crystals appeared to be practically identical for the studied ytterbium concentrations. Raman scattering spectrum of YbAl3(BO3)4 crystal has been measured. Group theory analysis of the optical absorption spectra is made, and new energy structure of the ground and excited states of Yb3+ ion, based on the experimental data obtained, is presented. Transformation of the local environment of Yb3+ ion depending on temperature has been found out. Spectrum of luminescence has been calculated from the absorption spectrum by reciprocity method with the use of the proposed energy structure.

AB - Temperature dependence of Yb3+ optical absorption spectrum has been studied in crystals YbxTm1-xAl3(BO3)4 (x = 0.1, 0.2 and 1) in the temperature range 1.7-293 K. The spectra of the crystals appeared to be practically identical for the studied ytterbium concentrations. Raman scattering spectrum of YbAl3(BO3)4 crystal has been measured. Group theory analysis of the optical absorption spectra is made, and new energy structure of the ground and excited states of Yb3+ ion, based on the experimental data obtained, is presented. Transformation of the local environment of Yb3+ ion depending on temperature has been found out. Spectrum of luminescence has been calculated from the absorption spectrum by reciprocity method with the use of the proposed energy structure.

KW - Crystal growth

KW - Electronic band structure

KW - Insulators

KW - Optical spectroscopy

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