Some properties of the a+b → C reaction-diffusion system with initially separated components

Haim Taitelbaum, Shlomo Havlin, James E. Kiefer, Benes Trus, George H. Weiss

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104 Scopus citations

Abstract

We study some properties of the A+B→C reaction-diffusion system with initially separated components, first analyzed by means of an asymptotic scaling argument by Gàlfi and Ràcz. We show that, in contrast to the asymptotic result that predicts that the rate of production of C goes like t-1, at early times it is shown to increase as t1/2. Deviations from this behavior appear at times inversely proportional to the reaction constant. Analogous crossover properties appear in the kinetic behavior of the reaction front. A second part of the study is concerned with the same chemical reaction on a fractal surface. When the substrate is a percolation cluster at criticality, both the maximum production rate and the width of the reaction zone differ considerably from those for the homogeneous space.

Original languageEnglish
Pages (from-to)873-891
Number of pages19
JournalJournal of Statistical Physics
Volume65
Issue number5-6
DOIs
StatePublished - Dec 1991

Keywords

  • Reaction-diffusion equation
  • exact enumeration method
  • fractal medium
  • percolation system

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