TY - JOUR
T1 - Solvent Polarity and the Anomeric Effect
AU - Fuchs, Benzion
AU - Ellencweig, Aviyakar
AU - Tartakovsky, Evgeny
AU - Aped, Pinchas
PY - 1986/3
Y1 - 1986/3
N2 - Polar solvents enhance the anomeric effect. This surprising turnabout follows from the NMR data and calculated dipole moments of dioxane derivatives such as 1 and 2. Accordingly, polar solvents stabilize the diaxial conformation in 2, RSiMe3, tBu; in these compounds μeq ≈ μax. Contributions by quadrupole moments etc. Were not taken into account. (Figure Presented.)
AB - Polar solvents enhance the anomeric effect. This surprising turnabout follows from the NMR data and calculated dipole moments of dioxane derivatives such as 1 and 2. Accordingly, polar solvents stabilize the diaxial conformation in 2, RSiMe3, tBu; in these compounds μeq ≈ μax. Contributions by quadrupole moments etc. Were not taken into account. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=84985630869&partnerID=8YFLogxK
U2 - 10.1002/anie.198602871
DO - 10.1002/anie.198602871
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AN - SCOPUS:84985630869
SN - 0570-0833
VL - 25
SP - 287
EP - 289
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 3
ER -