Solar-Light-Driven Photocatalytic Activity of Novel Sn@C-Dots-Modified TiO2 Catalyst

Vijay Bhooshan Kumar, Nina Perkas, Ze'ev Porat, Aharon Gedanken

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

The photocatalytic activity of titanium dioxide (TiO2) has already been investigated and compared with that of other materials. The main goal of the current study is to functionalize TiO2 with tin-doped carbon dots (Sn@C-dots/TiO2) and explore the activity of this composite as a photocatalyst for the photodegradation of dye molecules. The new composite Sn@C-dots/TiO2 was prepared by a two-step sonochemical reaction: a) Formation of Sn@C-dots by ultrasonic irradiation of molten tin immersed in polyethylene glycol at 260 °C; b) Addition of TiO2 and further sonication to induce the adhesion of the Sn@C-dots on the surface of the TiO2. The resulting composite was examined as a photocatalyst for the photodegradation of methylene blue and crystal violet under solar radiation and was found to exhibit better activity than commercial TiO2 or C-dots/TiO2. Doping C-dots with Sn and making hybrid Sn@C-dots/TiO2 nanocomposites opens a new type of photocatalytic materials.

Original languageEnglish
Pages (from-to)6683-6688
Number of pages6
JournalChemistrySelect
Volume2
Issue number23
DOIs
StatePublished - 11 Aug 2017

Bibliographical note

Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Funding

The authors are grateful to Ortal Lidor-Shalev for her help with the TEM measurements, to Daniel Raichman for the Raman measurements and to Merav Muallem for the HR-SEM measurements, all of the Department of Chemistry, Bar-Ilan University, Israel.

FundersFunder number
Bar-Ilan University

    Keywords

    • Photocatalyst
    • Sn@C-dots
    • Sn@C-dots/TiO
    • solar light
    • ultrasonic irradiation

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