Slow motional NMR lineshapes for very anisotropic diffusion: I = 1 nuclei

Eva Meirovitch; Jack H. Freed

doi:10.1016/0009-2614(79)80520-5

Slow motional NMR lineshapes for very anisotropic diffusion: I = 1 nuclei

Eva Meirovitch
, Jack H. Freed

Cornell University

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

A general method to analyze NMR show motional lineshapes is extended to I = 1 nuclei and illustrated on ²H NMR lineshapes of a clathrate hydrate of tetrahydrofuran (THF-d₈). It is shown that "ring puckering" could be the dominant mode of motion for the enclathrated THF-d₈ molecule, whereas several other models are inconsistent with experiment.

Original language	English
Pages (from-to)	311-316
Number of pages	6
Journal	Chemical Physics Letters
Volume	64
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(79)80520-5
State	Published - 1 Jul 1979
Externally published	Yes

Bibliographical note

Funding Information:
* Supported by NSF Grant = CHE77-26996

Funding

* Supported by NSF Grant = CHE77-26996

Funders	Funder number
National Science Foundation	CHE77-26996

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10.1016/0009-2614(79)80520-5

Cite this

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abstract = "A general method to analyze NMR show motional lineshapes is extended to I = 1 nuclei and illustrated on 2H NMR lineshapes of a clathrate hydrate of tetrahydrofuran (THF-d8). It is shown that {"}ring puckering{"} could be the dominant mode of motion for the enclathrated THF-d8 molecule, whereas several other models are inconsistent with experiment.",

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AB - A general method to analyze NMR show motional lineshapes is extended to I = 1 nuclei and illustrated on 2H NMR lineshapes of a clathrate hydrate of tetrahydrofuran (THF-d8). It is shown that "ring puckering" could be the dominant mode of motion for the enclathrated THF-d8 molecule, whereas several other models are inconsistent with experiment.

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Slow motional NMR lineshapes for very anisotropic diffusion: I = 1 nuclei

Abstract

Bibliographical note

Funding

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