Singularity in the degree of dissociation near a critical point

M. Gitterman

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

Anomalies in the degree of dissociation near a critical point of a ternary mixture are analyzed for a reaction of the type AB+C. The concentration- temperature curve has, at the critical point, an infinite slope (T-Tc)-(-1), where is the critical index. An isobutyric acid and water mixture, which consists of four components, has the same singularity in the charge density near a critical point. In any of the anomalies in the electrical conductivity in this mixture, or in similar systems, the singularity in the charge density must be considered.

Original languageEnglish
Pages (from-to)358-360
Number of pages3
JournalPhysical Review A
Volume28
Issue number1
DOIs
StatePublished - 1983

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