Singlet oxygen production by peptide-coated quantum dot-photosensitizer conjugates

James M. Tsay, Michael Trzoss, Lixin Shi, Xiangxu Kong, Matthias Selke, Michael E. Jung, Shimon Weiss

Research output: Contribution to journalArticlepeer-review

272 Scopus citations

Abstract

Peptide-coated quantum dot-photosensitizer conjugates were developed using novel covalent conjugation strategies on peptides which overcoat quantum dots (QDs). Rose bengal and chlorin e6, photosensitizers (PSs) that generate singlet oxygen in high yield, were covalently attached to phytochelatin-related peptides. The photosensitizer-peptide conjugates were subsequently used to overcoat green- and red-emitting CdSe/CdS/ZnS nanocrystals. Generation of singlet oxygen could be achieved via indirect excitation through Förster (fluorescence) resonance energy transfer (FRET) from the nanocrystals to PSs, or by direct excitation of the PSs. In the latter case, by using two color excitations, the conjugate could be simultaneously used for fluorescence imaging and singlet oxygen generation. Singlet oxygen quantum yields as high as 0.31 were achieved using 532-nm excitation wavelengths.

Original languageEnglish
Pages (from-to)6865-6871
Number of pages7
JournalJournal of the American Chemical Society
Volume129
Issue number21
DOIs
StatePublished - 30 May 2007
Externally publishedYes

Funding

FundersFunder number
National Institute of Biomedical Imaging and BioengineeringR01EB000312
National Center for Research ResourcesR01RR014891

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