Silylation of hydroxyketones by silicon chlorine derivatives

F. S. Mukhametov; R. M. Eliseenkova; E. E. Korshin

doi:10.1007/bf00958277

Silylation of hydroxyketones by silicon chlorine derivatives

F. S. Mukhametov, R. M. Eliseenkova, E. E. Korshin

Russian Academy of Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of 3-methyl-3-hydroxy-2-butanone (an α-hydroxyketone) with dimethyl-dichlorosilane gave 2,2,4,4-tetramethyl-5-methylene-1,3,2-dioxasilolane. The silylation of β-hydroxyketones leads to acyclic mono- and bis(γ-ketoalkoxy)silanes.

Original language	English
Pages (from-to)	1963-1965
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	39
Issue number	9
DOIs	https://doi.org/10.1007/bf00958277
State	Published - Sep 1990
Externally published	Yes

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title = "Silylation of hydroxyketones by silicon chlorine derivatives",

abstract = "The reaction of 3-methyl-3-hydroxy-2-butanone (an α-hydroxyketone) with dimethyl-dichlorosilane gave 2,2,4,4-tetramethyl-5-methylene-1,3,2-dioxasilolane. The silylation of β-hydroxyketones leads to acyclic mono- and bis(γ-ketoalkoxy)silanes.",

author = "Mukhametov, {F. S.} and Eliseenkova, {R. M.} and Korshin, {E. E.}",

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AU - Korshin, E. E.

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N2 - The reaction of 3-methyl-3-hydroxy-2-butanone (an α-hydroxyketone) with dimethyl-dichlorosilane gave 2,2,4,4-tetramethyl-5-methylene-1,3,2-dioxasilolane. The silylation of β-hydroxyketones leads to acyclic mono- and bis(γ-ketoalkoxy)silanes.

AB - The reaction of 3-methyl-3-hydroxy-2-butanone (an α-hydroxyketone) with dimethyl-dichlorosilane gave 2,2,4,4-tetramethyl-5-methylene-1,3,2-dioxasilolane. The silylation of β-hydroxyketones leads to acyclic mono- and bis(γ-ketoalkoxy)silanes.

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Silylation of hydroxyketones by silicon chlorine derivatives

Abstract

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