Semiconductor to metal transition in bilayer phosphorene under normal compressive strain

Aaditya Manjanath, Atanu Samanta, Tribhuwan Pandey, Abhishek K. Singh

Research output: Contribution to journalArticlepeer-review

80 Scopus citations


Phosphorene, a two-dimensional analog of black phosphorous, has been a subject of immense interest recently, due to its high carrier mobilities and a tunable bandgap. So far, tunability has been predicted to be obtained with very high compressive/tensile in-plane strains, and vertical electric field, which are difficult to achieve experimentally. Here, we show using density functional theory based calculations the possibility of tuning electronic properties by applying normal compressive strain in bilayer phosphorene. A complete and fully reversible semiconductor to metal transition has been observed at strain, which can be easily realized experimentally. Furthermore, a direct to indirect bandgap transition has also been observed at strain, which is a signature of unique band-gap modulation pattern in this material. The absence of negative frequencies in phonon spectra as a function of strain demonstrates the structural integrity of the sheets at relatively higher strain range. The carrier mobilities and effective masses also do not change significantly as a function of strain, keeping the transport properties nearly unchanged. This inherent ease of tunability of electronic properties without affecting the excellent transport properties of phosphorene sheets is expected to pave way for further fundamental research leading to phosphorene-based multi-physics devices.

Original languageEnglish
Article number075701
Issue number7
StatePublished - 20 Feb 2015
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2015 IOP Publishing Ltd.


  • DFT
  • normal compressive strain
  • phosphorene


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