Self-Assembly of Simple Corroles, via Hydrogen Bonding and Coordination

Zeev Gross; Vinay Kumar Sharma; Irena Saltsman; Qiu Cheng Chen; Natalia Fridman

doi:10.1002/ejoc.202000086

Self-Assembly of Simple Corroles, via Hydrogen Bonding and Coordination

Zeev Gross
, Vinay Kumar Sharma
, Irena Saltsman
, Qiu Cheng Chen
, Natalia Fridman

Technion-Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The unique properties of pyrazole raised the interest of preparing a corrole containing one such moiety on its C¹⁰ position. Its single-crystal X-ray structure uncovers it to be a dimer wherein the two monomeric units are held together by very strong corrole-pyrazole NH···N hydrogen bonding interactions that lead to a very well self-assembled network. The corresponding gallium(III) complex is isolated as a trimer in which all hydrogen bonding interactions are between the pyrazole subunits. In contrast, a tetrameric coordination complex is formed from the gallium(III) complex of a corrole with a pyridyl moiety on C¹⁰.

Original language	English
Pages (from-to)	3142-3146
Number of pages	5
Journal	European Journal of Organic Chemistry
Volume	2020
Issue number	21
DOIs	https://doi.org/10.1002/ejoc.202000086
State	Published - 8 Jun 2020
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Keywords

Corrole
H-bonding
Pyrazole
Self-assembly

Access to Document

10.1002/ejoc.202000086

Cite this

@article{c13819b3a5a84ff589d1f5965a67c71b,

title = "Self-Assembly of Simple Corroles, via Hydrogen Bonding and Coordination",

abstract = "The unique properties of pyrazole raised the interest of preparing a corrole containing one such moiety on its C10 position. Its single-crystal X-ray structure uncovers it to be a dimer wherein the two monomeric units are held together by very strong corrole-pyrazole NH···N hydrogen bonding interactions that lead to a very well self-assembled network. The corresponding gallium(III) complex is isolated as a trimer in which all hydrogen bonding interactions are between the pyrazole subunits. In contrast, a tetrameric coordination complex is formed from the gallium(III) complex of a corrole with a pyridyl moiety on C10.",

keywords = "Corrole, H-bonding, Pyrazole, Self-assembly",

author = "Zeev Gross and Sharma, \{Vinay Kumar\} and Irena Saltsman and Chen, \{Qiu Cheng\} and Natalia Fridman",

note = "Publisher Copyright: {\textcopyright} 2020 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2020",

month = jun,

day = "8",

doi = "10.1002/ejoc.202000086",

language = "אנגלית",

volume = "2020",

pages = "3142--3146",

journal = "European Journal of Organic Chemistry",

issn = "1434-193X",

publisher = "Wiley-VCH Verlag",

number = "21",

}

TY - JOUR

T1 - Self-Assembly of Simple Corroles, via Hydrogen Bonding and Coordination

AU - Gross, Zeev

AU - Sharma, Vinay Kumar

AU - Saltsman, Irena

AU - Chen, Qiu Cheng

AU - Fridman, Natalia

PY - 2020/6/8

Y1 - 2020/6/8

N2 - The unique properties of pyrazole raised the interest of preparing a corrole containing one such moiety on its C10 position. Its single-crystal X-ray structure uncovers it to be a dimer wherein the two monomeric units are held together by very strong corrole-pyrazole NH···N hydrogen bonding interactions that lead to a very well self-assembled network. The corresponding gallium(III) complex is isolated as a trimer in which all hydrogen bonding interactions are between the pyrazole subunits. In contrast, a tetrameric coordination complex is formed from the gallium(III) complex of a corrole with a pyridyl moiety on C10.

AB - The unique properties of pyrazole raised the interest of preparing a corrole containing one such moiety on its C10 position. Its single-crystal X-ray structure uncovers it to be a dimer wherein the two monomeric units are held together by very strong corrole-pyrazole NH···N hydrogen bonding interactions that lead to a very well self-assembled network. The corresponding gallium(III) complex is isolated as a trimer in which all hydrogen bonding interactions are between the pyrazole subunits. In contrast, a tetrameric coordination complex is formed from the gallium(III) complex of a corrole with a pyridyl moiety on C10.

KW - Corrole

KW - H-bonding

KW - Pyrazole

KW - Self-assembly

UR - https://www.scopus.com/pages/publications/85082935761

U2 - 10.1002/ejoc.202000086

DO - 10.1002/ejoc.202000086

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:85082935761

SN - 1434-193X

VL - 2020

SP - 3142

EP - 3146

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 21

ER -

Self-Assembly of Simple Corroles, via Hydrogen Bonding and Coordination

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Cite this