Selectivity of Outer-Sphere Electron-Transfer Reactions. 3

Haim Cohen; Shlomo Efrima; Dan Meyerstein; Mordechi Nutkovich; Karl Wieghardt

doi:10.1021/ic00146a023

Selectivity of Outer-Sphere Electron-Transfer Reactions. 3

Haim Cohen, Shlomo Efrima, Dan Meyerstein, Mordechi Nutkovich, Karl Wieghardt

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Abstract

The study of the kinetics of the reductions of a series of binuclear (μ-carboxylato)bis(μ-hydroxo)bis[triamminecobalt(III)] complexes has been extended to more powerful reducing agents. It was found that for very exothermic reactions the selectivity becomes independent of the redox potential of the reductant. The results are analyzed in the frame of the full Marcus formalism.

Original language	English
Pages (from-to)	688-690
Number of pages	3
Journal	Inorganic Chemistry
Volume	22
Issue number	4
DOIs	https://doi.org/10.1021/ic00146a023
State	Published - Feb 1983
Externally published	Yes

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abstract = "The study of the kinetics of the reductions of a series of binuclear (μ-carboxylato)bis(μ-hydroxo)bis[triamminecobalt(III)] complexes has been extended to more powerful reducing agents. It was found that for very exothermic reactions the selectivity becomes independent of the redox potential of the reductant. The results are analyzed in the frame of the full Marcus formalism.",

author = "Haim Cohen and Shlomo Efrima and Dan Meyerstein and Mordechi Nutkovich and Karl Wieghardt",

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AU - Nutkovich, Mordechi

AU - Wieghardt, Karl

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AB - The study of the kinetics of the reductions of a series of binuclear (μ-carboxylato)bis(μ-hydroxo)bis[triamminecobalt(III)] complexes has been extended to more powerful reducing agents. It was found that for very exothermic reactions the selectivity becomes independent of the redox potential of the reductant. The results are analyzed in the frame of the full Marcus formalism.

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Selectivity of Outer-Sphere Electron-Transfer Reactions. 3

Abstract

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